Synthesis and spectral kinetic study of photoinduced processes of photochromic nitro-substituted indoline and benzothienopyrroline spiropyrans in solutions

被引:7
作者
Shirinian, V. Z. [2 ]
Barachevsky, V. A. [1 ]
Shimkin, A. A. [2 ]
Krayushkin, M. M. [2 ]
Mailian, A. K. [2 ]
Tsyganov, D. V. [2 ]
Vinter, O. A. [3 ]
Venidiktova, O. V. [1 ]
机构
[1] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia
[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[3] D Mendelyev Univ Chem Technol Russia, Moscow 125047, Russia
基金
俄罗斯基础研究基金会;
关键词
photochromism; aggregation; spectroscopy; kinetics; spiropyrans;
D O I
10.1007/s11172-010-0168-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nitro-substituted benzothienopyrroline spiropyrans containing substituents in the ben-zothienopyrroline moiety were synthesized. The comparative spectral kinetic study of the pho-tochromic transformations of these compounds and their indoline analogs in solvents of various polarity was carried out. On the basis of the results obtained and literature data, the photoin-duced aggregation of molecules of the merocyanine form in weakly polar solvents was suggested.
引用
收藏
页码:828 / 832
页数:5
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