Do Cation•••p Interactions Always Need to be 1:1?

被引：38

作者：

Abraham, Sharon Achamma ^{[1
]}

Jose, Deepthi ^{[1
]}

Datta, Ayan ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Thiruvananthapuram, Sch Chem, Thiruvananthapuram 695016, Kerala, India

来源：

CHEMPHYSCHEM | 2012年 / 13卷 / 03期

关键词：

cation-pi interactions; charge transfer; density functional theory; intermolecular forces; supramolecular chemistry; DENSITY FUNCTIONALS; THERMOCHEMICAL KINETICS; CHARGE-DENSITY; BENZENE; MOLECULES; CHEMISTRY; DIANION;

D O I：

10.1002/cphc.201100996

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The more the better: Calculations and crystal-structure analyses show that a single electron-rich aromatic ring can simultaneously bind to two cations on its top and bottom π surfaces (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：695 / 698

页数：4

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