Crystal structures of the novel hydrated borates Ba2B5O9(OH), Sr2B5O9(OH) and Li2Sr8B22O41(OH)2

被引：25

作者：

McMillen, Colin ^{[1
,2
]}

Heyward, Carla ^{[1
,2
]}

Giesber, Henry ^{[3
]}

Kolis, Joseph ^{[1
,2
]}

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[2] Clemson Univ, COMSET, Clemson, SC 29634 USA

[3] Adv Photon Crystals, Ft Mill, SC 29708 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2011年 / 184卷 / 11期

基金：

美国国家科学基金会;

关键词：

Hydrothermal; Hydrated borate; Single crystal structure; Alkaline earth borate; HYDROTHERMAL SYNTHESIS; ABE(2)BO(3)F(2); HILGARDITE; CS; RB;

D O I：

10.1016/j.jssc.2011.08.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel hydrated borates Ba2B5O9(OH) (1), Sr2B5O9(OH) (2) and Li2Sr8B22O41(OH)(2) (3) have been synthesized hydrothermally and their structures determined. Compounds (1) and (2) are isostructural, crystallizing in space group P2(1)/c and having lattice parameters of a=6.6330(13) angstrom, b=8.6250(17) angstrom, c=14.680(3) angstrom, beta=93.46(3)degrees and a=6.4970(13) angstrom, b=8.4180(17) angstrom, c=14.177(3) angstrom, beta=94.35(3)degrees, respectively. Compound (3) crystallizes in P-1 with lattice parameters of a=6.4684(13) angstrom, b=8.4513(17) angstrom, c=14.881(3) angstrom, alpha=101.21(3)degrees, beta=93.96(3)degrees, gamma=90.67(3)degrees. While similar in their axis lengths, (3) differs greatly in structure and formulation from (1) and (2). The structure of (1) and (2) is contrasted to that of the well-known mineral hilgardite (Ca2B5O9Cl center dot H2O). (C) 2011 Elsevier Inc. All rights reserved.

引用

页码：2966 / 2971

页数：6

共 50 条

[41] Solvothermal Synthesis and Structure of Two New Borates Containing [B7O9(OH)5]2- and [B12O18(OH)6]6- Clusters
Zhang, Tian-Jiao
Pan, Rui
He, Huan
Yang, Bai-Feng
Yang, Guo-Yu
JOURNAL OF CLUSTER SCIENCE, 2016, 27 (02) : 625 - 633
[42] Syntheses and Crystal Structures of Two New Bismuth Hydroxyl Borates Containing [Bi2O2]2+ Layers: Bi2O2[B3O5(OH)] and Bi2O2[BO2(OH)]
Cong, Rihong
Sun, Junliang
Yang, Tao
Li, Mingrun
Liao, Fuhui
Wang, Yingxia
Lin, Jianhua
INORGANIC CHEMISTRY, 2011, 50 (11) : 5098 - 5104
[43] Ba2B13O19(OH)5•5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer
Liu, Kaitong
Han, Jian
Li, Fuming
Jin, Congcong
Yang, Zhihua
Mutailipu, Miriding
Pan, Shilie
JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 897
[44] The crystal structure of Tb3B5O11(OH)2
Teichtmeister, Tobias A.
Huppertz, Hubert
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (03): : 501 - 502
[45] Polar polymorphism: β-Ca2[B5O8(OH)]2[B(OH)3]•H2O-synthesis, structure and nonlinear optical property
Qiu, Qi-Ming
Li, Xu-Yan
Chen, Chong-An
Sun, Ke-Ning
Yang, Guo-Yu
JOURNAL OF SOLID STATE CHEMISTRY, 2021, 299
[46] Syntheses and Crystal Structures of Two New Organically Templated Borates: [(C2H10N2)]2[B14O20(OH)6] and [C8H22N4][B5O6(OH)4]2
Jiang Xiao
Liu Huan-Xin
Wu Shu-Li
Liang Yun-Xiao
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 28 (06) : 723 - 729
[47] Syntheses and Crystal Structures of Two New Organically Templated Borates:[(C2H10N2)]2[B14O20（OH）6] and [C8H22N4][B5O6（OH）4]2
江晓
刘欢欣
吴淑莉
梁云霄
Chinese Journal of Structural Chemistry, 2009, (06) : 723 - 729
[48] Crystal structure and magnetism of Fe2(OH)[B2O4(OH)]
Kurayoshi, Yotaro
Hara, Shigeo
Sato, Hirohiko
Frandsen, Cathrine
Morup, Steen
Rasmussen, Helge Kildahl
Nakamura, Shin
JOURNAL OF PHYSICS-CONDENSED MATTER, 2014, 26 (26)
[49] Solvothermal syntheses and crystal structures of two new nonmetal borates:: C4H10N2•B6O8(OH)2 and (NH3CH2CH2NH3)B5O8(OH)
Lu Gui-Qin
Yang Xin
Li Min
Shi Heng-Zhen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (03) : 257 - 262
[50] Solvothermal Syntheses and Crystal Structures of Two New Nonmetal Borates:C4H10N2·B6O8（OH）2 and （NH3CH2CH2NH3）B5O8（OH）
L Gui-Qina YANG Xinb LI Minc SHI Heng-Zhenc② a (School of Science
Chinese Journal of Structural Chemistry, 2007, (03) : 257 - 262

← 1 2 3 4 5 →