Thermodynamics properties of diatomic molecules with general molecular potential

被引:83
作者
Ikot, Akpan N. [1 ]
Chukwuocha, E. O. [1 ]
Onyeaju, M. C. [1 ]
Onate, C. A. [2 ]
Ita, B. I. [3 ]
Udoh, M. E. [1 ]
机构
[1] Univ Port Harcourt, Dept Phys, Theoret Phys Grp, Port Harcourt, Nigeria
[2] Landmark Univ, Dept Phys Sci, Omu Aran, Nigeria
[3] Univ Calabar, Dept Chem, Calabar, Nigeria
来源
PRAMANA-JOURNAL OF PHYSICS | 2018年 / 90卷 / 02期
关键词
Asymptotic iteration method; diatomic molecules; general molecular potential; partition function; PARTITION-FUNCTION; MORSE OSCILLATORS; DIMER;
D O I
10.1007/s12043-017-1510-0
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In this paper, the energy spectra of the general molecular potential are obtained using the asymptotic iteration method within the framework of non-relativistic quantum mechanics. With the energy spectrum obtained, the vibrational partition function is calculated in a closed form and is used to obtain an expression for other thermodynamic functions such as vibrational mean energy U, vibrational mean free energy F, vibrational entropy S and vibrational specific heat capacity C. These thermodynamic functions are studied for the electronic state X-1 Sigma(+)(g) of K-2 diatomic molecules.
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页数:9
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