Supramolecular electron transfer-based switching involving pyrrolic macrocycles. A new approach to sensor development?

被引：31
作者：
Bill, Nathan L. [1 ]
Trukhina, Olga [1 ,2 ]
Sessler, Jonathan L. [3 ]
Torres, Tomas [1 ,2 ]
机构：
[1] Univ Autonoma Madrid, Fac Ciencies, Dept Quim Organ, E-28049 Madrid, Spain
[2] IMDEA Nanociencia, Madrid 28049, Spain
[3] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 37期
基金：
美国国家科学基金会;
关键词：
WALL CARBON NANOTUBES; PHOTOINDUCED CHARGE SEPARATION; ANION-BINDING; ENERGY-TRANSFER; DOUBLE-DECKERS; FULLERENE; FLUORESCENT; PORPHYRIN; RECEPTOR; PHTHALOCYANINES;
D O I：
10.1039/c4cc10193f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This Feature focuses on pyrrolic macrocycles that can serve as switches via energy-or electron transfer (ET) mechanisms. Macrocycles operating by both ground state (thermodynamic) and photoinduced ET pathways are reviewed and their ability to serve as the readout motif for molecular sensors is discussed. The aim of this article is to highlight the potential utility of ET in the design of systems that perform molecular switching or logic functions and their applicability in chemical sensor development. The conceptual benefits of this paradigm are illustrated with examples drawn mostly from the authors' laboratories.
引用
收藏
页码：7781 / 7794
页数：14
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