N-[Amino(azido)methylidene]-4-methylbenzenesulfonamide

In the title molecule, C8H10N5O2S, the amino(azido)methyl and p-toluenesulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)degrees. An intramolecular N-H center dot center dot center dot O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, intermolecular N-H center dot center dot center dot O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N-H center dot center dot center dot O interaction along the b axis.