Removal of Acetaminophen from Aqueous Solution by Emulsion Liquid Membrane: Emulsion Stability Study

被引：29

作者：

Ahmad, A. L. ^{[1
]}

Zaulkiflee, N. D. ^{[1
]}

Kusumastuti, A. ^{[2
]}

Buddin, M. M. H. Shah ^{[3
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, Nibong Tebal 14300, Penang, Malaysia

[2] Univ Negeri Semarang, Fac Engn, Kampus UNNES Sekaran, Semarang 50229, Indonesia

[3] Univ Teknol MARA, Fac Chem Engn, Shah Alam 40450, Selangor, Malaysia

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 02期

关键词：

ULTRASOUND EMULSIFICATION; EMERGING CONTAMINANTS; ACIDIC-SOLUTIONS; WASTE-WATER; CHROMIUM VI; METAL-IONS; EXTRACTION; PERFORMANCE; ADSORPTION; SEPARATION;

D O I：

10.1021/acs.iecr.8b03562

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

This study focused on the investigation of emulsion stability, membrane breakage, and emulsion swelling of an emulsion liquid membrane for acetaminophen (ACTP) removal. Stability of the emulsion as well as its effectiveness in removing ACTP from aqueous solution were considered for the optimization of parameters. Parameters involved are carrier and surfactant concentration, emulsification time, as well as volume ratio of membrane to internal phase. The effects of membrane breakage and emulsion diameter on the removal capacity of ACTP were also studied. Results showed that the optimal conditions to produce a very stable emulsion and to achieve maximum ACTP removal efficiency were found to be 4 wt % of trioctylamine (TOA) and Span 80, W/O volume ratio of 3, and 10 min of emulsification time. The prepared emulsion was found to effectively remove 85% of ACTP at minimal membrane breakage of 0.19%.

引用

页码：713 / 719

页数：7

共 37 条

[11] EMULSION LIQUID MEMBRANES .1. PHENOMENON AND INDUSTRIAL APPLICATION [J].

DRAXLER, J ;

MARR, R .

CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1986, 20 (06) :319-329

[12]

Ebele Anekwe Jennifer, 2017, Emerging Contaminants, V3, P1, DOI 10.1016/j.emcon.2016.12.004

[13] Ultrasound emulsification: Effect of ultrasonic and physicochemical properties on dispersed phase volume and droplet size [J].

Gaikwad, Shashank G. ;

Pandit, Aniruddha B. .

ULTRASONICS SONOCHEMISTRY, 2008, 15 (04) :554-563

[14] Extraction of Co(II) from aqueous solution using emulsion liquid membrane [J].

Gasser, M. S. ;

El-Hefny, N. E. ;

Daoud, J. A. .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 151 (2-3) :610-615

[15]

Gheorghe A, 2008, UNIV POLITEH BUCHAR, V70, P23

[16] Chromium removal by emulsion liquid membrane using [BMIM]+[NTf2]- as stabilizer and TOMAC as extractant [J].

Goyal, Rahul Kumar ;

Jayakumar, N. S. ;

Hashim, M. A. .

DESALINATION, 2011, 278 (1-3) :50-56

[17] The effect of scale and interfacial tension on liquid-liquid dispersion in in-line SiIverson rotor-stator mixers [J].

Hall, Steven ;

Pacek, Andrzej W. ;

Kowalski, Adam J. ;

Cooke, Mike ;

Rothman, David .

CHEMICAL ENGINEERING RESEARCH & DESIGN, 2013, 91 (11) :2156-2168

[18] Removal of chromium from aqueous waste solution using liquid emulsion membrane [J].

Hasan, M. A. ;

Selim, Y. T. ;

Mohamed, K. M. .

JOURNAL OF HAZARDOUS MATERIALS, 2009, 168 (2-3) :1537-1541

[19]

Joshi H.C., 2012, ADV PURE APPL CHEM A

[20] Selective extraction and concentration of chromium(VI) from acidic solutions containing various metal ions through emulsion liquid membranes using Amber lite LA-2 [J].

Kumbasar, Recep Ali .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2010, 16 (05) :829-836

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