Synthesis of Aryl Nitriles via Aerobic Oxidative Cleavage of Aryl C=C Bonds with (NH 4 ) 2 CO 3 as the Nitrogen Source

被引：5

作者：

Zheng, Yi ^{[1
]}

Liu, Wenbo ^{[1
]}

Tian, Xinzhe ^{[1
]}

Ren, Yun-Lai ^{[1
]}

机构：

[1] Henan Agr Univ, Coll Sci, Zhengzhou 450002, Henan, Peoples R China

来源：

SYNLETT | 2022年 / 33卷 / 04期

基金：

中国国家自然科学基金;

关键词：

aromatic nitriles; arylethenes; carbon-carbon double bonds; oxidative cleavage; oxygen; ACCEPTORLESS DEHYDROGENATION; HETEROGENEOUS CATALYST; AROMATIC NITRILES; H BONDS; CYANATION; CONVERSION; ACCESS; AMINES; ACIDS; BENZONITRILES;

D O I：

10.1055/s-0041-1737761

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An aerobic oxidative method was developed for conversion of arylethenes to aromatic nitriles using (NH4)2CO3as the nitrogen source and Cu(NO3)2as the catalyst. The present method allowed a series of arylethenes to underwent oxidative cleavage of C=C bonds to give the targeted products in low to high yields. In addition, the present conditions are compatible with many groups such as alkyl, alkoxy, N,Ndimethylamino, chloro, bromo, iodo, ester, cyano group, and so on. © 2022 Georg Thieme Verlag. All rights reserved.

引用

页码：376 / 380

页数：5

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