The oxidative power of protonated hydrogen peroxide

被引：0

作者：

Oiestad, ÅML

Petersen, AC

Bakken, V

Vedde, J

Uggerud, E

机构：

[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

[2] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 07期

关键词：

D O I：

10.1002/1521-3773(20010401)40:73.0.CO;2-Y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple hydride-transfer mechanism to produce alkyl cations occurs when isolated protonated hydrogen peroxide (HOOH2+) attacks the C-H bonds of alkanes (except methane) [Eq. (1)]. The chemical properties of HOOH2+, which may serve as a model of the central catalytic motif of key biological systems, have been studied for the first time.

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页码：1305 / +

页数：6

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