Constructing 3D magnetic flower-like Fe3O4@SiO2@Co3O4@BiOCl heterojunction photocatalyst for degrading rhodamine B

被引:10
作者
Chen, Yan [1 ]
Su, Xuewei [1 ]
Ma, Mingliang [1 ]
Hou, Yongbo [1 ]
Lu, Chenggang [2 ]
Liu, Peizhe [1 ]
Ma, Yong [3 ]
Wan, Fei [1 ]
Yang, Ying [1 ]
Hu, Xinru [1 ]
Yu, Zhenqi [1 ]
机构
[1] Qingdao Univ Technol, Sch Civil Engn, Qingdao 266033, Peoples R China
[2] Qingdao Univ Technol, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China
[3] Shandong Univ Sci & Technol, Sch Mat Sci & Engn, Qingdao 266590, Peoples R China
关键词
Flower-like structure; Photocatalytic activity; RhB; Photodegradation mechanisms; BIOX X; DEGRADATION; NANOCOMPOSITES; NANOPARTICLES; MICROSPHERES; ELECTRODES; NANOSHEETS; MECHANISM; WATER; CL;
D O I
10.1007/s11356-022-21830-6
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work, the 3D magnetic flower-like Fe3O4@SiO2@Co3O4@BiOCl heterojunction photocatalyst was successfully prepared. The combination of BiOCl with Co3O4 favored to increase specific surface area and separate photo-generated carriers of the resulting composite, resulting in the improvement of catalytic efficiency. The photocatalytic activities of Fe3O4@SiO2@Co3O4@BiOCl were researched in details. In 50 min of visible light, the degradation efficiency for rhodamine B (RhB) of Fe3O4@SiO2@Co3O4@BiOCl was 98.41%. It still maintained 94.22% even after three tests. Furthermore, the photodegradation mechanisms were also investigated, indicating that the improved efficiency was ascribed to the superior separation of photo-induced electron-hole pairs. This study supplies a new perception to fabricate photocatalysts for actual uses.
引用
收藏
页码:87310 / 87318
页数:9
相关论文
共 48 条
[1]   Synthesis of Bi2S3/Bi2WO6 hierarchical microstructures for enhanced visible light driven photocatalytic degradation and photoelectrochemical sensing of ofloxacin [J].
Adhikari, Sangeeta ;
Kim, Do-Heyoung .
CHEMICAL ENGINEERING JOURNAL, 2018, 354 :692-705
[2]   A heterostructure BiOCl nanosheets/TiO2 hollow-tubes composite for visible light-driven efficient photodegradation antibiotic [J].
Bao, Sarenqiqige ;
Liang, Haiou ;
Li, Chunping ;
Bai, Jie .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2020, 397
[3]   Efficient photocatalytic degradation of herbicide glyphosate in water by magnetically separable and recyclable BiOBr/Fe3O4 nanocomposites under visible light irradiation [J].
Cao, Lidong ;
Ma, Dukang ;
Zhou, Zhaolu ;
Xu, Chunli ;
Cao, Chong ;
Zhao, Pengyue ;
Huang, Qiliang .
CHEMICAL ENGINEERING JOURNAL, 2019, 368 :212-222
[4]   Synthesis of Fe3O4 nanowire@CeO2/Ag nanocomposites with enhanced photocatalytic activity under sunlight exposure [J].
Chang, Jiali ;
Ma, Qingliang ;
Ma, Jianchao ;
Ma, Hongzhu .
CERAMICS INTERNATIONAL, 2016, 42 (10) :11827-11837
[5]   Engineering BiOX (X = Cl, Br, I) nanostructures for highly efficient photocatalytic applications [J].
Cheng, Hefeng ;
Huang, Baibiao ;
Dai, Ying .
NANOSCALE, 2014, 6 (04) :2009-2026
[6]   Facile and green synthesis of highly dispersed cobalt oxide (Co3O4) nano powder: Characterization and screening of its eco-toxicity [J].
Dubey, Shikha ;
Kumar, Jay ;
Kumar, Ashok ;
Sharma, Yogesh Chandra .
ADVANCED POWDER TECHNOLOGY, 2018, 29 (11) :2583-2590
[7]   Preparation, ferromagnetic and photocatalytic performance of NiO and hollow Co3O4 fibers through centrifugal-spinning technique [J].
Feng, Cong ;
Lin, Xuejun ;
Wang, Xinqiang ;
Liu, Hongjing ;
Liu, Benxue ;
Zhu, Luyi ;
Zhang, Guanghui ;
Xu, Dong .
MATERIALS RESEARCH BULLETIN, 2016, 74 :319-324
[8]   P-type Co3O4 nanoarrays decorated on the surface of n-type flower-like WO3 nanosheets for high-performance gas sensing [J].
Gui, Yanghai ;
Yang, Lele ;
Tian, Kuan ;
Zhang, Hongzhong ;
Fang, Shaoming .
SENSORS AND ACTUATORS B-CHEMICAL, 2019, 288 :104-112
[9]   A novel ceramic membrane coated with MnO2-Co3O4 nanoparticles catalytic ozonation for benzophenone-3 degradation in aqueous solution: Fabrication, characterization and performance [J].
Guo, Yang ;
Xu, Bingbing ;
Qi, Fei .
CHEMICAL ENGINEERING JOURNAL, 2016, 287 :381-389
[10]   Environmentally benign synthesis of Co3O4-SnO2 heteronanorods with efficient photocatalytic performance activated by visible light [J].
Huang, Ruting ;
Huang, Shoushuang ;
Chen, Dayong ;
Zhang, Qian ;
Thanh-Tung Le ;
Wang, Qing ;
Hu, Zhangjun ;
Chen, Zhiwen .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 542 :460-468