Two spiro[fluorene-9,8′-indolo[3,2,1-de]acridine] derivatives as host materials for green phosphorescent organic light-emitting diodes

被引:1
作者
Chen, Yi [1 ]
Wang, Bo [2 ]
Huang, Jinhai [3 ]
Wang, Lei [2 ]
Su, Jianhua [1 ]
机构
[1] East China Univ Sci & Technol, Inst Fine Chem, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Wuhan 430074, Hubei, Peoples R China
[3] Shanghai Taoe Chem Technol Co Ltd, Shanghai, Peoples R China
关键词
Green phosphorescent organic light-emitting diodes; Host materials; Spiro; Thermal stability; Indoloacridine; Benzofuran; Benzothiophene; HIGH-TRIPLET-ENERGY; BIPOLAR HOST; ELECTRON-TRANSPORT; THERMAL-STABILITY; EFFICIENT BLUE; HYBRIDS; MOLECULES;
D O I
10.1016/j.tsf.2017.09.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two host materials based on spiro[fluorene-9,8'-indolo[3,2,1-de]acridine] derivatives were designed and synthesized by introducing the benzofuran/benzothiophene unit to the spiro [fluorene-9,8'-indolo[3,2,1-de]acridine] unit. The two host materials exhibited high triplet energy level (> 2.65 eV) and the benzofuran-substituted derivative presented suitable glass transition temperature (> 130 degrees C). Their electrochemical and photo-physical properties were also determined. The green phosphorescent organic light-emitting diodes based on the two host materials obtained electroluminescence performances with external quantum efficiencies of 14.3 +/- 0.1% and 11.9 +/- 0.1%, respectively.
引用
收藏
页码:96 / 102
页数:7
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