Thiourea derivatives of α-aminoacids.: Synthesis and characterization of Ni(II), Cu(II) and Pt(II) complexes with L-valinate derivatives.: Antifungal activity

被引：47
作者：
Criado, JJ [1 ]
Rodríguez-Fernandez, E
García, E
Hermosa, MR
Monte, E
机构：
[1] Univ Salamanca, Fac Farm, Dept Quim Inorgan, E-37007 Salamanca, Spain
[2] Univ Salamanca, Fac Farm, Dept Genet & Microbiol, E-37007 Salamanca, Spain
来源：
JOURNAL OF INORGANIC BIOCHEMISTRY | 1998年 / 69卷 / 1-2期
关键词：
D O I：
10.1016/S0162-0134(97)10030-7
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The preparation of metal complexes with 2-[(3,3'-diethylthioureido)phenylmethylamino]-3-methylbutyric acid methyl ester, Hetv, or 3-methyl-2'-{[morpholine-4-carbothioylimino)phenylmethyl]amino}-butyric acid methyl ester, Hmtv, has been achieved. The complexes obtained with formulae of Ni(etv)(2), Cu(mtv)(2).2H(2)O and Pt(Hmtv)Cl-2, were studied and characterized by elemental analysis, electrical conductivity in solution, IR and UV-VIS spectra, FAB+ and electron impact (EI) mass spectrometry, H-1- and C-13-NMR, ESR, magnetic susceptibility, atomic absorption spectrometry and thermal analysis. Their antifungal activity was studied against the plant pathogenic fungi Colletotrichum fragariae, Rhizoctonia solani and Phoma betae. (C) 1998 Elsevier Science Inc. All rights reserved.
引用
收藏
页码：113 / 119
页数：7
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