Densities, Viscosities, Speeds of Sound, and Refractive Indices of Binary Mixtures of 2-Octanol with Chlorobenzenes

被引：17

作者：

Bhatia, Subhash C. ^{[1
]}

Sangwan, Jasbir ^{[1
]}

Rani, Ruman ^{[1
]}

Bhatia, Rachna ^{[1
]}

机构：

[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India

来源：

INTERNATIONAL JOURNAL OF THERMOPHYSICS | 2011年 / 32卷 / 10期

关键词：

Chlorobenzenes; Excess molar volume; Molar refraction; 2-Octanol; ISENTROPIC COMPRESSIBILITIES; ORGANIC LIQUIDS; HEAT-CAPACITIES; ULTRASONIC SPEEDS; GROUP ADDITIVITY; EXCESS VOLUMES; PLUS;

D O I：

10.1007/s10765-011-1087-7

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Densities, rho, viscosities, eta, speeds of sound, u, and refractive indices, n (D), of binary liquid mixtures of 2-octanol with 1,2-dichlorobenzene, 1,3-dichlorobenzene, and 1,2,4-trichlorobenzene have been measured over the entire range of composition at 298.15 K, 303.15 K, and 308.15 K and at atmospheric pressure. From the experimental data of the density, speed of sound, viscosity, and refractive index, the values of the excess molar volume, V (E), deviations in isentropic compressibility, Delta kappa (S) , and deviations in molar refraction, Delta R have been calculated. The calculated excess and deviation functions have been analyzed in terms of molecular interactions and structural effects.

引用

页码：2027 / 2039

页数：13

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