Pd(II)-Catalyzed para-Selective C-H Arylation of Monosubstituted Arenes

被引：277

作者：

Wang, Xisheng ^{[1
]}

Leow, Dasheng ^{[1
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 35期

基金：

美国国家卫生研究院;

关键词：

CATALYZED ORTHO-ARYLATION; BOND FORMATION; REDUCTIVE ELIMINATION; OXIDATIVE ARYLATION; FUNCTIONALIZATION; ACTIVATION; ELECTRON; BENZENE; COMPLEXES; BIPHENYL;

D O I：

10.1021/ja206572w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd-catalyzed highly para-selective C-H arylation of monosubstituted arenes (including toluene) is developed for the first time using an F+ reagent as a bystanding oxidant. This finding provides a new retrosynthetic disconnection for para-substituted biaryl synthesis via C-H/C-H cross-coupling.

引用

页码：13864 / 13867

页数：4

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