Solubility of sebacic acid in binary water plus ethanol solvent mixtures

被引:38
|
作者
Xia, Qing [1 ]
Zhang, Feng-Bao [1 ]
Zhang, Guo-Liang [1 ]
Ma, Jian-Cheng [1 ]
Zhao, Lei [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
来源
关键词
D O I
10.1021/je7005314
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubilities of sebacic acid in binary ethanol + water solvent mixtures were measured by the dynamic method using, a laser monitoring observation technique at a temperature range from (288 to 352) K. The mole fraction of ethanol in the solvent mixtures ranges from 0 to 1. The melting temperature and enthalpy of fusion of sebacic acid were determined by differential scanning calorimetry. The experimental results show that the slope of the solubility-temperature curve increases significantly with an increase in the mole fraction of ethanol in the solvent. The Wilson equation is applied to describe measured systems. The model parameters of the Wilson equation were expressed as a function of temperature.
引用
收藏
页码:838 / 840
页数:3
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