Phase-Field Simulation of Spinodal Decomposition in Mn-Cu Alloys

被引:4
作者
Sigala-Garcia, Dario A. [1 ]
Lopez-Hirata, Victor M. [1 ]
Saucedo-Munoz, Maribel L. [1 ]
Dorantes-Rosales, Hector J. [1 ]
Villegas-Cardenas, Jose D. [1 ]
机构
[1] Natl Polytech Inst, Higher Educ Sch Chem Engn & Extract Ind, Mexico City 07300, DF, Mexico
关键词
phase decomposition; growth kinetics; Mn-rich Mn-Cu alloys; microstructure evolution; phase field method; MARTENSITIC-TRANSFORMATION; FE; PRECIPITATION; BEHAVIOR; KINETICS; SYSTEM; MODEL;
D O I
10.3390/met12071220
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The spinodal decomposition was studied in the aged Mn-40 at. %Cu, Mn-30 at. %Cu, Mn-20 at. %Cu alloys using a phase-field model based on the Cahn-Hillard equation, considering a subregular solution model and the energy contribution of the magnetic behavior. The simulations were performed at aging temperatures of 300, 400, and 500 degrees C for times from 1 to 240 min. The growth kinetics of the Mn concentration profiles with time indicated clearly that the phase decomposition of the supersaturated solid solution gamma into a mixture of Mn-rich gamma' and Cu-rich gamma phases occurred by the spinodal decomposition mechanism. Moreover, the phase decomposition at the early stages of aging exhibited the characteristic morphology of spinodal decomposition, an interconnected and percolated microstructure of the decomposed phases. The most rapid growth kinetics of spinodal decomposition occurred for the aging of Mn-20 and 30 at. %Cu alloys because of the higher driving force. The presence of the phase decomposition is responsible for the increase in hardness, as well as the improvement of the damping capacity of Mn-Cu alloys.
引用
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页数:15
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