Heterogeneous Co3O4/AgO nanorods for conductometric triethylamine sensing at 90 °C

被引：30

作者：

Lei, Guanglu ^{[1
]}

Lou, Chengming ^{[1
]}

Li, Zishuo ^{[1
]}

Xie, Jiayue ^{[1
]}

Lu, Guocai ^{[1
]}

Pan, Hongyin ^{[1
]}

Mei, Houshan ^{[1
]}

Liu, Xianghong ^{[1
,2
]}

Zhang, Jun ^{[1
]}

机构：

[1] Qingdao Univ, Coll Phys, Ctr Marine Observat & Commun, Qingdao 266071, Peoples R China

[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China

来源：

SENSORS AND ACTUATORS B-CHEMICAL | 2022年 / 351卷

基金：

中国国家自然科学基金;

关键词：

Gas sensor; Cobalt oxide; Heterostructure; Low temperature; Triethylamine; GAS SENSOR; HIGH-SENSITIVITY; ANODE MATERIALS; PERFORMANCE; TEMPERATURE; ACETONE; HETEROSTRUCTURES; NANOSHEETS; NANOSTRUCTURES; TRANSPORT;

D O I：

10.1016/j.snb.2021.131005

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

To achieve room or low temperature gas sensitivity with low power consumption has been a challenging task for metal oxide semiconductor gas sensors. In this work, heterogeneous Co3O4 /AgO nanorods are synthesized by wet-chemical method. The structural and compositional characterizations show that AgO nanoparticles are highly dispersed on the surface of Co3O4 nanorods. It is found that the AgO nanoparticles can trigger both catalytic and electronic sensitization that lead to improved sensor properties. Consequently the sensor based on Co3O4/AgO delivers a remarkable response to triethylamine (TEA) at room temperature (RT) and the best response at 90 degrees C, which is much lower compared to that (195 degrees C) of pristine Co3O4. In addition, the sensor shows fast response time (44 s) and low limit of detection (65 ppb), good selectivity and repeatability for TEA detection. This work provides an effective strategy for developing low temperature gas sensors based on p-type metal oxides.

引用

页数：10

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