Heterogeneous Co3O4/AgO nanorods for conductometric triethylamine sensing at 90 °C

被引:30
作者
Lei, Guanglu [1 ]
Lou, Chengming [1 ]
Li, Zishuo [1 ]
Xie, Jiayue [1 ]
Lu, Guocai [1 ]
Pan, Hongyin [1 ]
Mei, Houshan [1 ]
Liu, Xianghong [1 ,2 ]
Zhang, Jun [1 ]
机构
[1] Qingdao Univ, Coll Phys, Ctr Marine Observat & Commun, Qingdao 266071, Peoples R China
[2] Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China
来源
SENSORS AND ACTUATORS B-CHEMICAL | 2022年 / 351卷
基金
中国国家自然科学基金;
关键词
Gas sensor; Cobalt oxide; Heterostructure; Low temperature; Triethylamine; GAS SENSOR; HIGH-SENSITIVITY; ANODE MATERIALS; PERFORMANCE; TEMPERATURE; ACETONE; HETEROSTRUCTURES; NANOSHEETS; NANOSTRUCTURES; TRANSPORT;
D O I
10.1016/j.snb.2021.131005
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
To achieve room or low temperature gas sensitivity with low power consumption has been a challenging task for metal oxide semiconductor gas sensors. In this work, heterogeneous Co3O4 /AgO nanorods are synthesized by wet-chemical method. The structural and compositional characterizations show that AgO nanoparticles are highly dispersed on the surface of Co3O4 nanorods. It is found that the AgO nanoparticles can trigger both catalytic and electronic sensitization that lead to improved sensor properties. Consequently the sensor based on Co3O4/AgO delivers a remarkable response to triethylamine (TEA) at room temperature (RT) and the best response at 90 degrees C, which is much lower compared to that (195 degrees C) of pristine Co3O4. In addition, the sensor shows fast response time (44 s) and low limit of detection (65 ppb), good selectivity and repeatability for TEA detection. This work provides an effective strategy for developing low temperature gas sensors based on p-type metal oxides.
引用
收藏
页数:10
相关论文
共 50 条
  • [21] Studying the humidity sensing behavior of MWCNTs boosted with Co3O4 nanorods
    Taha, Walaa M.
    Morsy, Mohamed
    Nada, Nadra A.
    Ibrahim, Medhat
    DIAMOND AND RELATED MATERIALS, 2022, 121
  • [22] PdPt Nanoparticle-Functionalized α-Fe2O3 Hollow Nanorods for Triethylamine Sensing
    Li, Gaojie
    Ma, Zhiheng
    Hu, Qingmin
    Zhang, Dan
    Fan, Yu
    Wang, Xiaohong
    Chu, Xiangfeng
    Xu, Jiaqiang
    ACS APPLIED NANO MATERIALS, 2021, 4 (10) : 10921 - 10930
  • [23] Controlled synthesis and CO sensing potentials of size-tunable highly-uniform mesoporous Co3O4 nanospheres
    Chen, Kuan-Wei
    Tsai, Ju-Heng
    Chen, Chun-Hua
    JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 816
  • [24] Mechanism of enhancing the formaldehyde sensing properties of Co3O4 via Ag modification
    Bai, Shouli
    Liu, Haiyan
    Sun, Jianhua
    Tian, Ye
    Luo, Ruixian
    Li, Dianqing
    Chen, Aifan
    RSC ADVANCES, 2015, 5 (60) : 48619 - 48625
  • [25] Tailoring oxygen sensing characteristics of Co3O4 nanostructures through Gd doping
    Fareed, S.
    Medwal, R.
    Vas, Joseph Vimal
    Khan, Ijaz A.
    Rawat, Rajdeep Singh
    Rafiq, M. A.
    CERAMICS INTERNATIONAL, 2020, 46 (07) : 9498 - 9506
  • [26] Sandwich-like composites of double-layer Co3O4 and reduced graphene oxide and their sensing properties to volatile organic compounds
    Yuan, Zhenyu
    Zhao, Junpeng
    Meng, Fanli
    Qin, Wenbo
    Chen, Yaru
    Yang, Minghui
    Ibrahim, Medhat
    Zhao, Yong
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 793 : 24 - 30
  • [27] Co3O4/ZnO nanocomposites for gas-sensing applications
    Liu, Yuanjun
    Zhu, Guoxing
    Chen, Junzhi
    Xu, Huan
    Shen, Xiaoping
    Yuan, Aihua
    APPLIED SURFACE SCIENCE, 2013, 265 : 379 - 384
  • [28] Co3O4/MoS2 Nanostructures for NOx Sensing
    Fathima, Nazia
    Jha, Ravindra Kumar
    Bhat, Navakanta
    ACS APPLIED NANO MATERIALS, 2022, 5 (06) : 7754 - 7766
  • [29] Heterogeneous Co3O4/Carbon Nanofibers for Low Temperature Triethylamine Detection: Mechanistic Insights by Operando DRIFTS and DFT
    Lou, Chengming
    Wang, Kai
    Liu, Xianghong
    Li, Xinyu
    Wang, Hui
    Li, Lihong
    Zheng, Wei
    Zhang, Jun
    ADVANCED MATERIALS INTERFACES, 2022, 9 (01):
  • [30] Design of p-n heterojunction on mesoporous ZnO/Co3O4 nanosheets for triethylamine sensor
    Gong, Fei-Long
    Peng, Ming-Xing
    Yue, Li-Juan
    Chen, Jun-Li
    Xie, Ke-Feng
    Zhang, Yong-Hui
    CHEMICAL PHYSICS LETTERS, 2021, 779