Structural determination of the La@C82 isomer

被引：111

作者：

Akasaka, T

Wakahara, T

Nagase, S

Kobayashi, K

Waelchli, M

Yamamoto, K

Kondo, M

Shirakura, S

Maeda, Y

Kato, T

Kako, M

Nakadaira, Y

Gao, X

Van Caemelbecke, E

Kadish, KM

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[3] Tokyo Metropolitan Univ, Dept Chem, Grad Sch Sci, Hachioji, Tokyo 1920397, Japan

[4] Bruker Japan, Tsukuba, Ibaraki 3050051, Japan

[5] Power Reactor & Nucl Fuel Dev Corp, Tokai, Ibaraki 3191100, Japan

[6] Univ Electrocommun, Dept Appl Phys & Chem, Chofu, Tokyo 1828585, Japan

[7] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2001年 / 105卷 / 15期

关键词：

D O I：

10.1021/jp003930d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

stable diamagnetic monoanion of the La@C-82 isomer was electrochemically prepared and isolated in order to disclose its cage symmetry. By measuring the C-13 NMR spectrum of the anion, it was determined for the first time that the isomer has C-s symmetry, as was also confirmed by density functional calculations.

引用

页码：2971 / 2974

页数：4

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