Preparation and structures of tetrameric and dimeric manganese carbonyl complexes incorporating thiosalicylato ligands

被引：20

作者：

Depree, CV ^{[1
]}

Main, L ^{[1
]}

Nicholson, BK ^{[1
]}

Roberts, K ^{[1
]}

机构：

[1] UNIV WAIKATO, SCH SCI & TECHNOL, HAMILTON, NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 517卷 / 1-2期

关键词：

manganese; carbonyl; cluster; thiosalicylato ligand; crystal structure;

D O I：

10.1016/0022-328X(95)06109-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Orthomanganated N,N-dimethylbenzamide reacts with SO2 to give a tetra-manganese complex Mn-4(thsa)(2)(CO)(16) (thsa=thiosalicylate=2-thiobenzoate di-anion) which an X-ray structure determination shows to contain four Mn(CO)(4) units linked by two triply bridging (S,O,O) thsa ligands. Another product identified after aerobic work-up was the disulphide [2-((OOC)-O--)C6H4S-](2). Reaction of thiosalicylic acid with BrMn(CO)(5) in the presence of Et(3)N gave good yields of [Et(3)NH](2)[Mn-2(thsa)(2)(CO)(6)], the anion of which contains two [Mn(eta(2)-thsa)(CO)(3)](-) units doubly-linked via the S atoms.

引用

页码：201 / 207

页数：7

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