Preparation and structures of tetrameric and dimeric manganese carbonyl complexes incorporating thiosalicylato ligands

被引：20

作者：

Depree, CV ^{[1
]}

Main, L ^{[1
]}

Nicholson, BK ^{[1
]}

Roberts, K ^{[1
]}

机构：

[1] UNIV WAIKATO, SCH SCI & TECHNOL, HAMILTON, NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 517卷 / 1-2期

关键词：

manganese; carbonyl; cluster; thiosalicylato ligand; crystal structure;

D O I：

10.1016/0022-328X(95)06109-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Orthomanganated N,N-dimethylbenzamide reacts with SO2 to give a tetra-manganese complex Mn-4(thsa)(2)(CO)(16) (thsa=thiosalicylate=2-thiobenzoate di-anion) which an X-ray structure determination shows to contain four Mn(CO)(4) units linked by two triply bridging (S,O,O) thsa ligands. Another product identified after aerobic work-up was the disulphide [2-((OOC)-O--)C6H4S-](2). Reaction of thiosalicylic acid with BrMn(CO)(5) in the presence of Et(3)N gave good yields of [Et(3)NH](2)[Mn-2(thsa)(2)(CO)(6)], the anion of which contains two [Mn(eta(2)-thsa)(CO)(3)](-) units doubly-linked via the S atoms.

引用

页码：201 / 207

页数：7

共 50 条

[21] Trinuclear and dinuclear manganese complexes of 2/4-formylbenzoic acid oxime ligands: Syntheses and crystal structures
Shen Chao-Jun
Chen Jian-Shan
Sheng Tian-Lu
Fu Rui-Biao
Hu Sheng-Min
Xiang Sheng-Chang
Qin Zheng-Tao
Wang Xin
He Yi-Ming
Wu Xin-Tao
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (08) : 899 - 906
[22] Effect of Auxiliary Ligands on the Architectures of Manganese Complexes Constructed by N-Heterocyclic Ligands: Syntheses, Structures, and Properties
Zhang, Huiping
Wang, Ying
Guan, Lei
Yin, Pengpeng
INDIAN JOURNAL OF HETEROCYCLIC CHEMISTRY, 2024, 34 (01) : 7 - 13
[23] Manganese (II) complexes containing carbacylamidophosphate ligands: Synthesis, molecular structures and computational investigation
Ghaziani, Fatemeh
Afshar, Farzaneh
Maghsoud, Yazdan
Gholivand, Khodayar
JOURNAL OF MOLECULAR STRUCTURE, 2019, 1181 : 61 - 70
[24] Discrete polynuclear manganese(II) complexes with thiacalixarene ligands: synthesis, structures and photophysical properties
Suffren, Yan
O'Toole, Niall
Hauser, Andreas
Jeanneau, Erwann
Brioude, Arnaud
Desroches, Cedric
DALTON TRANSACTIONS, 2015, 44 (17) : 7991 - 8000
[25] Syntheses and structures of the first polynuclear manganese guanidine complexes and of the first manganese complexes containing mono-protonated bis-guanidine ligands
Neuba, Adam
Herres-Pawlis, Sonja
Floerke, Ulrich
Henkel, Gerald
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (04): : 771 - 777
[26] Syntheses and Structures of Monomeric and Dimeric Ternary Complexes of Copper(II) with 2,2′-Bipyridyl and Carboxylate Ligands
Batool, Syeda Shahzadi
Gilani, Syeda Rubina
Tahir, Muhammad Nawaz
Harrison, William T. A.
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2016, 642 (23): : 1364 - 1368
[27] Mono- and bimetallic manganese-carbonyl complexes and clusters bearing imidazol(in) ium-2-dithiocarboxylate ligands
Beltran, Tomas F.
Zaragoza, Guillermo
Delaude, Lionel
DALTON TRANSACTIONS, 2017, 46 (06) : 1779 - 1788
[28] Synthesis, spectroscopic and structural characterisation of molybdenum, tungsten and manganese carbonyl complexes of tetrathio- and tetraseleno-ether ligands
Levason, William
Ollivere, Luke P.
Reid, Gillian
Tsoureas, Nikolaos
Webster, Michael
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (15) : 2299 - 2308
[29] Synthesis, characterization and crystal structures of some tungsten and triosmium carbonyl complexes with monopyridyl and dipyridyl azo ligands
Wong, WY
Cheung, SH
Lee, SM
Leung, SY
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 596 (1-2) : 36 - 45
[30] Structures and Bonding of η2-Bridging CO Ligands and Their Influence on the Structures and Rearrangements of Higher Nuclearity Metal Carbonyl Cluster Complexes
Adams, Richard D.
Zhang, Qiang
ORGANOMETALLICS, 2013, 32 (18) : 5171 - 5179

← 1 2 3 4 5 →