Mechanism of visible-light photoisomerization of a rhenium(I) carbonyl-diimine complex

被引：39

作者：

Gindensperger, Etienne ^{[1
]}

Koeppel, Horst ^{[2
]}

Daniel, Chantal ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, Lab Chim Quant, Inst Chim,UMR 7177, F-67070 Strasbourg, France

[2] Univ Heidelberg, Inst Phys Chem, D-69120 Heidelberg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 43期

关键词：

STILBENE; LIGAND; DYNAMICS;

D O I：

10.1039/c0cc02661a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of photoisomerization of a Re(I) carbonyl-diimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin-orbit and vibronic couplings, we provide a clear picture of this complicated multi-step process.

引用

页码：8225 / 8227

页数：3

共 12 条

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