Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

被引：25

作者：

Chen, Kai ^{[1
]}

He, Pei ^{[1
]}

Zhang, Shuai ^{[1
]}

Li, Pengfei ^{[1
]}

机构：

[1] Xi An Jiao Tong Univ, FIST, Ctr Organ Chem, 99 Yanxiang Rd, Xian 710054, Shaanxi, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 58期

基金：

美国国家科学基金会;

关键词：

CROSS-COUPLING REACTIONS; C-H BORYLATION; CATALYZED STANNYLATION; STILLE REACTION; SOLAR-CELLS; ALKYNES; ARYLSTANNANES; FLUORINATION; STANNANES; GERMANIUM;

D O I：

10.1039/c6cc01135g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.

引用

页码：9125 / 9128

页数：4

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