Modelling the kinetics of UV/H2O2 oxidation of dichloroacetic acid

被引：5

作者：

Zalazar, C. S. ^{[1
]}

Labas, M. D. ^{[1
]}

Lovato, M. E. ^{[1
]}

Brandi, R. J. ^{[1
]}

Cassano, A. E. ^{[1
]}

机构：

[1] Univ Nacl Litoral & CONICET, INTEC, RA-3000 Santa Fe, Argentina

来源：

WATER SCIENCE AND TECHNOLOGY | 2007年 / 55卷 / 12期

关键词：

dichloroacetic acid; kinetics; UV/hydrogen peroxide; water pollution;

D O I：

10.2166/wst.2007.377

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The intrinsic reaction kinetics of the decomposition of dichloroacetic acid (DCA) using UV/H2O2 was studied. A complete mathematical model, including the effect of the absorbed radiation intensities and H2O2 concentration was developed. The results of the kinetic measurements were analysed using a complete mathematical model of the experimental device that was used for the laboratory operation (a differential reactor inside a recycle). In this way it was expected to obtain intrinsic kinetic parameters. Experimental data agree well with theoretical predictions esmploying just two kinetic parameters derived from the proposed reaction mechanism.

引用

页码：31 / 35

页数：5

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