A comment on the formation of N-C bonds via reactions of anionic dinitrogen complexes with organic halides: X-ray crystallographic structure of trans-[W(CN)(NNCHOCH2CH2CH2)(dppe)(2)]

被引：3

作者：

Hughes, DL ^{[1
]}

Ibrahim, SK ^{[1
]}

Ali, HM ^{[1
]}

Pickett, CJ ^{[1
]}

机构：

[1] JOHN INNES CTR PLANT SCI RES,NITROGEN FIXAT LAB,NORWICH NR4 7UH,NORFOLK,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 519卷 / 1-2期

关键词：

dinitrogen complexes; tungsten; silicon; crystal structure; diazenides;

D O I：

10.1016/S0022-328X(96)06173-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of trans-[W(N-2)(CN)(dppe)(2)](-) with Me(3)SiCH(2)I in tetrahydrofuran gives a tetrahydrofuranyldiazenide product, trans-[W(CN)(NNCHOCH2CH2CH2)(dppe)(2)], the formation of which confirms that N-C bond formation involving reactions between anionic dinitrogen complexes and organic halides can occur by a single electron transfer/radical coupling mechanism. The structure of the diazenide was established crystallographically.

引用

页码：273 / 275

页数：3

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