Inorganic Hybrid Materials with Encapsulated Polyoxometalates

被引：45

作者：

Dufaud, Veronique ^{[1
]}

Lefebvre, Frederic ^{[2
]}

机构：

[1] Univ Lyon, CNRS ENS Lyon, Chim Lab, UMR 5182, F-69364 Lyon 07, France

[2] Univ Lyon, CNRS CPE Lyon, Lab Chim Catalyse Polymeres & Procedes, UMR 5265, F-69622 Villeurbanne, France

来源：

MATERIALS | 2010年 / 3卷 / 01期

关键词：

polyoxometalates; encapsulation; inorganic hybrid material; nanocomposites; MESOPOROUS SILICA; BIODIESEL PRODUCTION; HETEROPOLY COMPOUNDS; METAL-OXIDES; SOLID ACID; COMPOSITE; CATALYSIS; FRAMEWORK; H3PW12O40; EFFICIENT;

D O I：

10.3390/ma3010682

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review describes the synthesis and characterization of inorganic materials containing polyoxometalates encapsulated in oxide matrices. Examples illustrating key aspects in terms of synthesis and applications are presented according to the nature of the final hybrid material: those based on non-structured silicas, on mesostructured silicas, on macrostructured silicas and on other oxides. In each part, key points of the synthetic protocols are highlighted and structural features and properties of the resultant hybrid nanocomposites are discussed.

引用

页码：682 / 703

页数：22

共 58 条

[1]

Beck J.S., 1992, AM CHEM SOC, V114, P10834, DOI DOI 10.1021/JA00053A020

[2]

Blanford CF, 2001, ADV MATER, V13, P401, DOI 10.1002/1521-4095(200103)13:6<401::AID-ADMA401>3.0.CO

[3]

2-7

[4] Toward new organic/inorganic superlattices: Keggin polyoxometalates in Langmuir and Langmuir-Blodgett films [J].

ClementeLeon, M ;

Agricole, B ;

Mingotaud, C ;

GomezGarcia, CJ ;

Coronado, E ;

Delhaes, P .

LANGMUIR, 1997, 13 (08) :2340-2347

[5] Application of the Langmuir-Blodgett technique to polyoxometalates: Towards new magnetic films [J].

ClementeLeon, M ;

Mingotaud, C ;

Agricole, B ;

GomezGarcia, CJ ;

Coronado, E ;

Delhaes, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (10) :1114-1116

[6] New insights into the encapsulation and stabilization of heteropolyacids inside the pore walls of mesostructured silica materials [J].

Dufaud, Veronique ;

Lefebvre, Frederic ;

Niccolai, Gerald P. ;

Aouine, Mimoun .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (08) :1142-1150

[7] Polyoxometalate-zirconia (POM/ZrO2) nanocomposite prepared by sol-gel process: A green and recyclable photocatalyst for efficient and selective aerobic oxidation of alcohols into aldehydes and ketones [J].

Farhadi, Saeid ;

Zaidi, Masoumeh .

APPLIED CATALYSIS A-GENERAL, 2009, 354 (1-2) :119-126

[8] Bifunctional conversion of n-decane over HPW heteropoly acid incorporated into SBA-15 during synthesis [J].

Gagea, B. C. ;

Lorgouilloux, Y. ;

Altintas, Y. ;

Jacobs, P. A. ;

Martens, J. A. .

JOURNAL OF CATALYSIS, 2009, 265 (01) :99-108

[9] True microporosity and surface area of mesoporous SBA-15 silicas as a function of synthesis temperature [J].

Galarneau, A ;

Cambon, H ;

Di Renzo, F ;

Fajula, F .

LANGMUIR, 2001, 17 (26) :8328-8335

[10] Preparation, characterization and photochemical properties of ordered macroporous hybrid silica materials based on monovacant Keggin-type polyoxometalates [J].

Guo, YH ;

Yang, Y ;

Hu, CW ;

Guo, CX ;

Wang, EB ;

Zou, YC ;

Feng, SH .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) :3046-3052

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