Asymmetric nuclear motion of the F1s-ionized state in BF3 probed by quadruple-ion-coincidence momentum imaging

被引:17
作者
De Fanis, A [1 ]
Saito, N
Machida, M
Okada, K
Chiba, H
Cassimi, A
Dörner, R
Koyano, I
Ueda, K
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
[2] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan
[3] Natl Metrol Inst Japan, AIST, Tsukuba, Ibaraki 3058568, Japan
[4] Himeji Inst Technol, Dept Mat Sci, Kamigori 6781297, Japan
[5] Hiroshima Univ, Dept Phys Sci, Higashihiroshima 7398526, Japan
[6] Univ Caen, CNRS, ISMRA, CEA,CIRIL, F-14070 Caen 5, France
[7] Goethe Univ Frankfurt, Inst Kernphys, D-60486 Frankfurt, Germany
关键词
D O I
10.1103/PhysRevA.69.022506
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Using the quadruple-ion-coincidence momentum imaging technique, we find that the momentum correlation of the four atomic ions departed from one BF34+ parent molecular ion produced via multiple Auger decay after F 1s ionization exhibits asymmetric fragmentation in which the B+ ion is ejected in the direction opposite to one of the F+ ions. This observation provides evidence of symmetry lowering, from D-3h to C-3v in the F 1s-ionized state.
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页数:4
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