Silver(I)-Dipyridylpyrimidine Complexes with Argentophilic Interactions and Their Luminescent Properties

被引：0

作者：

Lu Mei-Fang ^{[1
]}

Wang Peng ^{[1
]}

Zhao Yue ^{[1
]}

Wang Zhi-Bin ^{[1
]}

Sun Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 09期

关键词：

silver(I) complex; argentophilic interaction; pi-pi interaction; photoluminescence property; ENCAPSULATED ACETYLIDE DIANION; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; DOUBLE SALTS; SILVER ACETYLIDE; METAL; FRAMEWORK; DISCRETE; NETWORKS; CYANIDE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two silver(I) complexes [Ag-2(L)(2)](CF3COO)(2) (1) and [Ag-2(L)(2)](CF3SO3)(2) (2) [L=2-methyl-4,6-di(pyridin-3-yl)pyrimidine] were synthesized and characterized by elemental, IR and single crystal X-ray diffraction analyses. The binuclear complexes 1 and 2 form infinite 1D chains through argentophilic interactions, and further extend into 2D supramolecular networks by pi-pi interactions. The photoluminescent measurements reveal that complex 2 exhibits fluorescent emission in the solid state at room temperature and the luminescent decay time was determined. CCDC; 827908, 1; 827909, 2.

引用

页码：1842 / 1846

页数：5

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