Biodiesel from soybean oil, castor oil and their blends Oxidative stability by PDSC and rancimat

被引：31

作者：

Dantas, M. B. ^{[1
]}

Albuquerque, A. R. ^{[1
]}

Soledade, L. E. B. ^{[1
]}

Queiroz, N. ^{[1
]}

Maia, A. S. ^{[1
]}

Santos, I. M. G. ^{[1
]}

Souza, A. L. ^{[1
]}

Cavalcanti, E. H. S. ^{[2
]}

Barro, A. K. ^{[3
,4
]}

Souza, A. G. ^{[1
]}

机构：

[1] Univ Fed Paraiba, LACOM Lab Combustiveis & Mat, CCEN, Dept Quim, BR-58059900 Joao Pessoa, Paraiba, Brazil

[2] Inst Nacl Tecnol, LACOR Lab Corrosao & Protecao Rio de Janeiro, BR-20081312 Rio De Janeiro, Brazil

[3] Univ Fed Maranhao, Sao Luis, MA, Brazil

[4] ANP Agencia Nacl Petr Gas Nat & Biocombustiveis, BR-20090004 Rio De Janeiro, Brazil

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2011年 / 106卷 / 02期

关键词：

Biodiesel; Blends; Rancimat; PDSC; ESTERS; METHANOL; INDEX;

D O I：

10.1007/s10973-011-1410-3

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Even not being described in the EN 14112 standard, PDSC has been used for the determination of the biodiesel oxidative stability, by OIT and OT measurements. In this study, biodiesel blends were obtained by mixing soybean (BES) and castor (BEM) ethyl esters and its induction periods were measured by Rancimat and PDSC. The blends (BSM (X) ) showed intermediate values of OSI, OT, and OIT, compared with BES and BEM. Although, the molar fraction of the components varied linearly in BSM (X) , OSI, OT, and OIT values increased exponentially in relation to the castor biodiesel amount in the blends. Introduction of castor oil biodiesel increased the blend stability, so the BSM(30) blend reached the OSI limit of 6 h. OSI, OIT, and OT showed a high-linear correlation, pointing out that PDSC can be used in the analysis of this kind of biodiesel, with a smaller sample and analysis time, as compared to Rancimat. The use of biodiesel blends was a good alternative in the correction of the oxidative stability of the final product without the need of antioxidant addition.

引用

页码：607 / 611

页数：5

共 18 条

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