Polymer synthesis by in vitro enzyme catalysis

被引：649
作者：
Gross, RA [1 ]
Kumar, A [1 ]
Kalra, B [1 ]
机构：
[1] Polytech Univ, Dept Chem & Chem Engn, NSF IUCRC Biocatalyis & Bioproc Macromol, Metrotech Ctr 3, Brooklyn, NY 11201 USA
来源：
CHEMICAL REVIEWS | 2001年 / 101卷 / 07期
关键词：
D O I：
10.1021/cr0002590
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The polymer synthesis by in vitro enzyme catalysis was discussed. The enzyme-catalyzed condensation polymerizations which included self-condensation reactions and AA-BB type enzymatic polytransesterifications were studied. The effect of reaction parameters such as solvent, enzyme concentration, reaction water content and reaction temperature on polyester synthesis was also elaborated.
引用
收藏
页码：2097 / 2124
页数：28
相关论文
共 190 条
[1]   ENZYME CATALYZED PREPARATION OF 6-O-ACYLGLUCOPYRANOSIDES [J].
ADELHORST, K ;
BJORKLING, F ;
GODTFREDSEN, SE ;
KIRK, O .
SYNTHESIS-STUTTGART, 1990, (02) :112-115
[2]   SYNTHESIS AND CHARACTERIZATION OF POLYMERS PRODUCED BY HORSERADISH-PEROXIDASE IN DIOXANE [J].
AKKARA, JA ;
SENECAL, KJ ;
KAPLAN, DL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (11) :1561-1574
[3]   Enzyme-catalyzed ring-opening copolymerization of 5-methyl-5-benzyloxycarbonyl-1,3-dioxan-2-one (MBC) with trimethylene carbonate (TMC): Synthesis and characterization [J].
Al-Azemi, TF ;
Harmon, JP ;
Bisht, KS .
BIOMACROMOLECULES, 2000, 1 (03) :493-500
[4]   Novel functional polycarbonate by lipase-catalyzed ring-opening polymerization of 5-methyl-5-benzyloxycarbonyl-1,3-dioxan-2-one [J].
Al-Azemi, TF ;
Bisht, KS .
MACROMOLECULES, 1999, 32 (20) :6536-6540
[5]   Enzymatic synthesis and characterization of a novel water-soluble polyaniline: Poly(2,5-diaminobenzenesulfonate) [J].
Alva, KS ;
Kumar, J ;
Marx, KA ;
Tripathy, SK .
MACROMOLECULES, 1997, 30 (14) :4024-4029
[6]  
Andresen O, 1995, PROGR BIOTECHNOL, V10, P343, DOI 10.1016/S0921-0423(06)80115-2
[7]   MICROBIAL-PRODUCTION, STRUCTURE ELUCIDATION AND BIOCONVERSION OF SOPHOROSE LIPIDS [J].
ASMER, HJ ;
LANG, S ;
WAGNER, F ;
WRAY, V .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1988, 65 (09) :1460-1466
[8]   ENZYMATIC-SYNTHESIS OF POLYESTERS BY LIPASE-CATALYZED POLYTRANSESTERIFICATION [J].
ATHAWALE, VD ;
GAONKAR, SR .
BIOTECHNOLOGY LETTERS, 1994, 16 (02) :149-154
[9]   CONTROLLED FREE-RADICAL POLYMERIZATION OF PHENOL DERIVATIVES BY ENZYME-CATALYZED REACTIONS IN ORGANIC-SOLVENTS [J].
AYYAGARI, MS ;
MARX, KA ;
TRIPATHY, SK ;
AKKARA, JA ;
KAPLAN, DL .
MACROMOLECULES, 1995, 28 (15) :5192-5197
[10]  
BANKOVA M, 2000, POLYMER, V41, P1822
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