On the [2,3] sigmatropic rearrangement of allylic nitro compounds

被引：15

作者：

Alameda-Angulo, C

Quiclet-Sire, B

Schmidt, E

Zard, SZ ^{[1
]}

机构：

[1] Ecole Polytech, Lab Synth Organ Assoc, F-91128 Palaiseau, France

[2] Ecole Polytech, CNRS, F-91128 Palaiseau, France

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 16期

关键词：

D O I：

10.1021/ol051196g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite.

引用

页码：3489 / 3492

页数：4

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