Synthesis, crystal structure, and properties of three lead(II) complexes based on the 1,10-phenanthroline ligand

被引：0

作者：

Li, De-Jun ^{[1
]}

Tang, Shi-Li ^{[1
]}

Ma, Feng-Jie ^{[1
]}

Zhang, Lu-Lin ^{[1
]}

Cheng, Yuan-Zheng ^{[1
]}

Zhang, Li-Ping ^{[1
]}

机构：

[1] Weifang Med Univ, Sch Pharm, Weifang 261053, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2022年 / 77卷 / 09期

关键词：

1; 10-phenanthroline; 3; 5-dinitrobenzoate; crystal structure; lead(II); supramolecular structure; TETREL BONDING INTERACTIONS; 3,5-DINITROBENZOIC ACID; PI-HOLE; ZN(II); 2,2'-BIPYRIDINE; ADDUCTS; PB(II); CU(II);

D O I：

10.1515/znb-2022-0035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new lead(II) complexes containing the 1,10-phenanthroline ligand, [Pb(phen)(2)(3,5-DNB)(2)] (1), [Pb(phen)(2)(3,5-DNB)(NO3)](2)center dot H2O (2), and [Pb(phen)(HCOO)(NO3)(H2O)]( n ) (3) (phen = 1,10-phenanthroline, 3,5-DNB = 3,5-dinitrobenzoate anion) have been synthesized and characterized by elemental analyses, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyses (TGA), and single-crystal X-ray diffraction. The complexes 1 and 2 are monomeric species, whereas complex 3 is a one-dimensional polymer. In the three complexes, the ligand phen creates a number of pi center dot center dot center dot pi stacking interactions and hydrogen bonds, which play an important role in extending complexes 1-3 to supramolecular architectures. The Pb(II) ion of complexes 1 and 2 shows hemidirected geometry with noncovalent Pb center dot center dot center dot O/C tetrel bonds formed which further stabilize the supramolecular structures.

引用

页码：601 / 609

页数：9

共 35 条

[31] Decorating Metal Nitrate with a Coplanar Bipyridine Moiety: A Simple and General Method for Fabricating Photochromic Complexes [J].

Xu, Fei ;

Liu, Ai-Ju ;

Han, Song-De ;

Pan, Jie ;

Wang, Guo-Ming .

CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (14) :4709-4714

[32]

Zhang YM, 2011, CHEM J CHINESE U, V32, P2181

[33] Syntheses, crystal structure and characterizations of a new lead (II) coordination compound [Pb(phen)(NO3)2(H2O)]n [J].

Zhao, Jin-An ;

Wang, Yu-Ling ;

Wang, Yu-Ting ;

Fan, Yao-Ting ;

Hou, Hong-Wei .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (02) :109-113

[34] Two 2D Co(II)/Mn(II) coordination polymers based on the quinoline-2,3-dicarboxylate ligand: synthesis, crystal structure, and fluorescence properties [J].

Zhao, Ya-Li ;

Weng, Qi-Ying ;

Xie, Yu-Qian ;

Li, Jia-Ming .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2022, 77 (01) :17-23

[35] Syntheses, structures and selective dye adsorption of five formic-based coordination polymers prepared by in-situ hydrolysis of N, N′-dimethylformamide [J].

Zhu, Zheng ;

Meng, Xiang-min ;

Zhang, Dong-mei ;

Zhang, Xia ;

Wang, Mei ;

Jin, Fan ;

Fan, Yu-hua .

JOURNAL OF SOLID STATE CHEMISTRY, 2017, 248 :109-118

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