Synthesis, crystal structure, and properties of three lead(II) complexes based on the 1,10-phenanthroline ligand

被引：0

作者：

Li, De-Jun ^{[1
]}

Tang, Shi-Li ^{[1
]}

Ma, Feng-Jie ^{[1
]}

Zhang, Lu-Lin ^{[1
]}

Cheng, Yuan-Zheng ^{[1
]}

Zhang, Li-Ping ^{[1
]}

机构：

[1] Weifang Med Univ, Sch Pharm, Weifang 261053, Peoples R China

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2022年 / 77卷 / 09期

关键词：

1; 10-phenanthroline; 3; 5-dinitrobenzoate; crystal structure; lead(II); supramolecular structure; TETREL BONDING INTERACTIONS; 3,5-DINITROBENZOIC ACID; PI-HOLE; ZN(II); 2,2'-BIPYRIDINE; ADDUCTS; PB(II); CU(II);

D O I：

10.1515/znb-2022-0035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new lead(II) complexes containing the 1,10-phenanthroline ligand, [Pb(phen)(2)(3,5-DNB)(2)] (1), [Pb(phen)(2)(3,5-DNB)(NO3)](2)center dot H2O (2), and [Pb(phen)(HCOO)(NO3)(H2O)]( n ) (3) (phen = 1,10-phenanthroline, 3,5-DNB = 3,5-dinitrobenzoate anion) have been synthesized and characterized by elemental analyses, Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyses (TGA), and single-crystal X-ray diffraction. The complexes 1 and 2 are monomeric species, whereas complex 3 is a one-dimensional polymer. In the three complexes, the ligand phen creates a number of pi center dot center dot center dot pi stacking interactions and hydrogen bonds, which play an important role in extending complexes 1-3 to supramolecular architectures. The Pb(II) ion of complexes 1 and 2 shows hemidirected geometry with noncovalent Pb center dot center dot center dot O/C tetrel bonds formed which further stabilize the supramolecular structures.

引用

页码：601 / 609

页数：9

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