High-activity, single-site mesoporous Pd/Al2O3 catalysts for selective aerobic oxidation of allylic alcohols

被引：350
|
作者：
Hackett, Simon E. J.
Brydson, Rik M.
Gass, Mhairi H.
Harvey, Ian
Newman, Andrew D.
Wilson, Karen
Lee, Adam F. [1 ]
机构：
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] SERC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England
[3] Univ Leeds, Inst Mat Res, Leeds LS2 9JT, W Yorkshire, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 45期
基金：
英国工程与自然科学研究理事会;
关键词：
heterogeneous catalysis; mesoporous materials; oxidation; palladium; X-ray absorption spectroscopy;
D O I：
10.1002/anie.200702534
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Pd does it alone: Tailored heterogeneous catalysts offer exciting, alternative, clean technologies for regioselective molecular transformations. A mesoporous alumina support stabilizes atomically dispersed PdII surface sites (see picture, C light gray, O red, Pd dark gray, Al purple, H white), thereby dramatically enhancing catalytic performance in the aerobic selective oxidation of alcohols. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8593 / 8596
页数：4
相关论文
共 50 条
  • [31] Infrared studies of CO oxidation by oxygen and by water over Pt/Al2O3 and Pd/Al2O3 catalysts
    Busca, Guido
    Finocchio, Elisabetta
    Sanchez Escribano, Vicente
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 113 : 172 - 179
  • [32] Effect of Fe-modified α-Al2O3 on the properties of Pd/α-Al2O3 catalysts in selective acetylene hydrogenation
    Tatiya Sangkhum
    Okorn Mekasuwandumrong
    Piyasan Praserthdam
    Joongjai Panpranot
    Reaction Kinetics and Catalysis Letters, 2009, 97 : 115 - 123
  • [33] Effect of Fe-modified α-Al2O3 on the properties of Pd/α-Al2O3 catalysts in selective acetylene hydrogenation
    Sangkhum, Tatiya
    Mekasuwandumrong, Okorn
    Praserthdam, Piyasan
    Panpranot, Joongjai
    REACTION KINETICS AND CATALYSIS LETTERS, 2009, 97 (01): : 115 - 123
  • [34] Hydrogen purification for fuel cells:: selective oxidation of carbon monoxide on Pd and FePd/Al2O3 catalysts
    Jain, SK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2005, 82 (12) : 1141 - 1146
  • [35] Methane combustion over Pd/γ-Al2O3 and Pd-VOx/γ-Al2O3 catalysts
    Neyertz, C
    Volpe, M
    Gigola, C
    APPLIED CATALYSIS A-GENERAL, 2004, 277 (1-2) : 137 - 145
  • [36] SELECTIVE POISONING OF AL2O3 CATALYSTS
    HIGHTOWE.JW
    JOURNAL OF CATALYSIS, 1967, 8 (03) : 298 - &
  • [37] SELECTIVE POISONING OF AL2O3 CATALYSTS
    MEDEMA, J
    HOUTMAN, JPW
    JOURNAL OF CATALYSIS, 1966, 6 (02) : 322 - &
  • [38] Oxidation behaviour and catalytic properties of Pd/Al2O3 catalysts in the total oxidation of methane
    Roth, D
    Gélin, P
    Kaddouri, A
    Garbowski, E
    Primet, M
    Tena, E
    CATALYSIS TODAY, 2006, 112 (1-4) : 134 - 138
  • [39] On the mechanism of selective CO oxidation on nanosized Au/γ-Al2O3 catalysts
    Gavril, D.
    Georgaka, A.
    Loukopoulos, V.
    Karaiskakis, G.
    Nieuwenhuys, B. E.
    GOLD BULLETIN, 2006, 39 (04) : 192 - 199
  • [40] On the mechanism of selective CO oxidation on nanosized Auγ-Al2O3 catalysts
    D Gavrila
    A Georgakab
    V Loukopoulosb
    G Karaiskakisb
    B E Nieuwenhuysa
    Gold Bulletin, 2006, 39 : 192 - 199
12345