Highly efficient and robust electrospun nanofibers for selective removal of acid dye

被引:32
作者
Qureshi, Umair Ahmed [1 ,2 ]
Khatri, Zeeshan [1 ,3 ]
Ahmed, Farooq [1 ]
Ibupoto, Abdul Sameeu [1 ]
Khatri, Muzamil [3 ]
Mahar, Faraz Khan [1 ]
Brohi, Rafi Zaman [4 ]
Kim, Ick Soo [3 ]
机构
[1] Mehran Univ Engn & Technol, Dept Text Engn, Nanomat Res Lab, Jamshoro 76062, Pakistan
[2] Govt Boys Degree Coll Qasimabad, Hyderabad 71000, Pakistan
[3] Shinshu Univ, ICCER, Inst Fiber Engn IFES, Nano Fus Technol Res Lab,Div Frontier Fibers, 3-15-1 Tokida, Ueda, Nagano 3868567, Japan
[4] Mehran Univ Engn & Technol, Dept Environm Engn, Jamshoro 76062, Pakistan
关键词
Filtration; Electrospinning; Nanofibers; Selectivity; Acid blue 117; Adsorption; AQUEOUS-SOLUTION; NYLON-6; NANOFIBERS; ADSORPTION CAPACITY; WATER-PURIFICATION; ANIONIC DYES; WASTE-WATER; SORPTION; ADSORBENT; EQUILIBRIUM; MEMBRANES;
D O I
10.1016/j.molliq.2017.08.129
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The highly efficient and economic nylon-6 nanofibers without pre/post-electrospinning treatment were prepared for the fast and selective removal of anionic dye. i.e., Acid Blue 117 (AB 117), in just 25 min of contact. This is the first time the application of pure nylon-6 nanofibers for dye removal is reported. Nylon-6, in nanofibers form, possessed greater adsorption capability compared to its pellet form. The adsorption data fitted well to pseudo second order and Freundlich isotherm. Nylon-6 nanofibers showed excellent efficiency for AB117 in single and higher selectivity in binary component system. The nanofibers were also used as a membrane for removing AB117 from continuous streams by varying the number of layers. The maximum adsorption capacity in batch mode was found 58.8 mg/g and 0.321 mg/cm(2) in continuous mode. The proposed nanofibers offer maximum permeation flux of 113.2 L/m(2).h which is much higher than conventional nanofiltration membranes with 10 L/m(2).h.bar. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:478 / 488
页数:11
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