Manganese Acetate in Pyrrolidinium Ionic Liquid as a Robust and Efficient Catalytic System for Epoxidation of Aliphatic Terminal Alkenes

被引：9
|
作者：
Ho, Kam-Piu [1 ]
Wong, Wing-Leung [1 ]
Lee, Lawrence Yoon Suk [1 ]
Lam, Kin-Ming [1 ]
Chan, Tak Hang [1 ]
Wong, Kwok-Yin [1 ]
机构：
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 09期
关键词：
catalysts; epoxidation; green chemistry; ionic liquid; manganese; HYDROGEN-PEROXIDE; SOLVENTS; OLEFINS; SELECTIVITY; EXAMPLE;
D O I：
10.1002/asia.201000109
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Green epoxides! A novel and simple ionic liquid/manganese acetate catalytic system has been developed for the rapid and selective oxidation of aliphatic terminal alkenes to epoxides. It provides an efficient, reusable, and scalable protocol for the green synthesis of epoxides from various aliphatic terminal alkenes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1970 / 1973
页数：4
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