Manganese Acetate in Pyrrolidinium Ionic Liquid as a Robust and Efficient Catalytic System for Epoxidation of Aliphatic Terminal Alkenes

被引：9
|
作者：
Ho, Kam-Piu [1 ]
Wong, Wing-Leung [1 ]
Lee, Lawrence Yoon Suk [1 ]
Lam, Kin-Ming [1 ]
Chan, Tak Hang [1 ]
Wong, Kwok-Yin [1 ]
机构：
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Kowloon, Hong Kong, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 09期
关键词：
catalysts; epoxidation; green chemistry; ionic liquid; manganese; HYDROGEN-PEROXIDE; SOLVENTS; OLEFINS; SELECTIVITY; EXAMPLE;
D O I：
10.1002/asia.201000109
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Green epoxides! A novel and simple ionic liquid/manganese acetate catalytic system has been developed for the rapid and selective oxidation of aliphatic terminal alkenes to epoxides. It provides an efficient, reusable, and scalable protocol for the green synthesis of epoxides from various aliphatic terminal alkenes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1970 / 1973
页数：4
相关论文
共 50 条
  • [1] A simple and effective catalytic system for epoxidation of aliphatic terminal alkenes with manganese(II) as the catalyst
    Ho, Kam-Piu
    Wong, Wing-Leung
    Lam, Kin-Ming
    Lai, Cheuk-Piu
    Chan, Tak Hang
    Wong, Kwok-Yin
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (26) : 7988 - 7996
  • [2] EFFICIENT CATALYTIC EPOXIDATION OF ALKENES BY A MANGANESE PORPHYRIN AND PERIODATE IN THE PRESENCE OF IMIDAZOLE
    MOHAJER, D
    TANGESTANINEJAD, S
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 240 - 241
  • [3] Efficient epoxidation of alkenes with sodium periodate catalyzed by manganese porphyrins in ionic liquid: Investigation of catalyst reusability
    Tangestaninejad, Shahram
    Moghadam, Majid
    Mirkhani, Valiollah
    Mohammadpoor-Baltork, Iraj
    Hajian, Robabeh
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (12) : 1501 - 1503
  • [4] An efficient epoxidation of terminal aliphatic alkenes over heterogeneous catalysts: when solvent matters
    Palumbo, C.
    Tiozzo, C.
    Ravasio, N.
    Psaro, R.
    Carniato, F.
    Bisio, C.
    Guidotti, M.
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (11) : 3832 - 3839
  • [5] Ultrasound and ionic liquid: An efficient combination to tune the mechanism of alkenes epoxidation
    Chatel, Gregory
    Goux-Henry, Catherine
    Kardos, Nathalie
    Suptil, Joel
    Andrioletti, Bruno
    Draye, Micheline
    ULTRASONICS SONOCHEMISTRY, 2012, 19 (03) : 390 - 394
  • [6] Mesoporous SBA-15 modified with manganese pyrazolylpyridine complexes for the catalytic epoxidation of terminal alkenes
    Tang, Jianyuan
    Zu, Yanhong
    Huo, Weitao
    Wang, Lei
    Wang, Jing
    Jia, Mingjun
    Zhang, Wenxiang
    Thiel, Werner R.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 355 : 201 - 209
  • [7] Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin
    Lai, TS
    Lee, SKS
    Yeung, LL
    Liu, HY
    Williams, ID
    Chang, CK
    CHEMICAL COMMUNICATIONS, 2003, (05) : 620 - 621
  • [8] Controlling the selectivity of the manganese/bicarbonate/hydrogen peroxide catalytic system by a biphasic pyrrolidinium ionic liquid/n-heptane medium
    Wong, Wing-Leung
    Ho, Kam-Piu
    Lee, Lawrence Yoon Suk
    So, Ming-Him
    Chan, Tak Hang
    Wong, Kwok-Yin
    APPLIED CATALYSIS A-GENERAL, 2013, 453 : 244 - 249
  • [9] Cobalt complex in a room temperature ionic liquid: A convenient recyclable reagent for catalytic epoxidation of cyclic alkenes
    Ramakrishna, Dileep
    Bhat, Badekai Ramachandra
    Hanumanthappa, Suresha Kumara T.
    COMPTES RENDUS CHIMIE, 2014, 17 (11) : 1071 - 1074
  • [10] Self-assembled ionic liquid based organosilica-titania: A novel and efficient catalyst for green epoxidation of alkenes
    Yari, Omolbanin
    Elhamifar, Dawood
    Shaker, Masoumeh
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2021, 940
12345