Effects of electrolyte recycling on desulfurization from bauxite water slurry electrolysis

被引:7
作者
Lu, Ai-jing [1 ,2 ]
Shen, Yi-qi [1 ]
Gong, Xu-zhong [1 ]
Wang, Zhi [1 ]
Wang, Yu-hua [1 ]
Wang, Ming-yong [1 ]
机构
[1] Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China
[2] Liaoning Tech Univ, Coll Environm Sci & Engn, Fuxin 123000, Peoples R China
基金
中国国家自然科学基金;
关键词
high sulfur bauxite; electrolysis; desulfurization; electrolyte; recycling; SULFUR REMOVAL; PYRITE; COAL; OXIDATION; KINETICS; PHASE; FERRATE(VI); BEHAVIOR; SULFIDE; IRON;
D O I
10.1016/S1003-6326(16)64280-2
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
To lower the cost of bauxite electrolysis desulfurization using NaOH solution as the supporting electrolyte, effects of electrolyte recycling on bauxite electrolysis desulfurization were investigated. The results indicate that electrode corrosion, cell voltage, the desulfurization rate and the pH value of the electrolyte have no obvious changes with the increase of cycle times. Additionally, there were some transitive valence S-containing ions in electrolyte after the electrolysis, such as SO32, S2O32. However, most of the sulfur in bauxite was eventually oxidized into SO42- into the electrolyte, and these S-containing ions did not affect the recycling utilization for electrolyte.
引用
收藏
页码:1714 / 1720
页数:7
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