Selective Synthesis of Facial and Meridianal Isomers of Alq3

被引：19

作者：

Tsuboi, Taiju ^{[1
]}

Torii, Yasuko ^{[2
]}

机构：

[1] Kyoto Sangyo Univ, Fac Engn, Kyoto 6038555, Japan

[2] Iwatani Chem Engn Ltd, Shiga, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2010年 / 529卷

关键词：

-Alq3; electroluminescence; facial; meridianal Alq3; organic light emitting diode; photoluminescence; LIGHT-EMITTING DEVICES; TRIS(8-HYDROXYQUINOLINE) ALUMINUM(III) ALQ(3); ORGANIC THIN-FILMS; STATE; NMR; FLUORESCENCE; POLYMORPHS; EMISSION; PACKING; PHASE;

D O I：

10.1080/15421406.2010.495672

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alq3 was synthesized by mixing 8-quinolinol and Al(OH)3 at about 95 degrees C. The reaction time of 24h leads to formation of -phase Alq3 which is formed by meridianal Alq3, while the reaction time of 100h leads to -Alq3 which is formed by facial Alq3. Unlike the conventional method, -Alq3 was obtained without heating -Alq3 at about 400 degrees C. The and phases were determined by X-ray diffraction, and confirmed by photoluminescence spectra with vibronic structure. Organic light emitting diode (OLED) fabricated using mer-Alq3 shows higher green Alq3 electroluminescence and longer lifetime than OLED fabricated using fac-Alq3.

引用

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页码：42 / 52

页数：11

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