Structure and dynamics of all of the stereoisomers of europium complexes of tetra(carboxyethyl) derivatives of dota:: ring inversion is decoupled from cooperative arm rotation in the RRRR and RRRS isomers

被引：85
作者：
Howard, JAK
Kenwright, AM
Moloney, JM
Parker, D
Port, M
Navet, M
Rousseau, O
Woods, M
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Guerbet SA, F-95943 Roissy, France
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 13期
关键词：
D O I：
10.1039/a802847h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The absolute configuration of the four stereoisomeric alpha-substituted derivatives of dota has been defined; in their Eu complexes, 2D-NMR methods have revealed that in solution ring inversion is independent of pendant arm rotation and the (RRRR)-[EuL1a] complex which in the solid state crystallises as a square antiprismatic structure.
引用
收藏
页码：1381 / 1382
页数：2
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  • [1] Lanthanide(III) chelates for NMR biomedical applications
    Aime, S
    Botta, M
    Fasano, M
    Terreno, E
    [J]. CHEMICAL SOCIETY REVIEWS, 1998, 27 (01) : 19 - 29
  • [2] Conformational and coordination equilibria on DOTA complexes of lanthanide metal ions in aqueous solution studied by H-1-NMR spectroscopy
    Aime, S
    Botta, M
    Fasano, M
    Marques, MPM
    Geraldes, CFGC
    Pubanz, D
    Merbach, AE
    [J]. INORGANIC CHEMISTRY, 1997, 36 (10) : 2059 - 2068
  • [3] NMR-STUDY OF SOLUTION STRUCTURES AND DYNAMICS OF LANTHANIDE(III) COMPLEXES OF DOTA
    AIME, S
    BOTTA, M
    ERMONDI, G
    [J]. INORGANIC CHEMISTRY, 1992, 31 (21) : 4291 - 4299
  • [4] LANTHANIDE(III) TETRAAMIDE MACROCYCLIC COMPLEXES AS SYNTHETIC RIBONUCLEASES - STRUCTURE AND CATALYTIC PROPERTIES OF [LA(TCMC)(CF3SO3)(ETOH)](CF3SO3)(2)
    AMIN, S
    MORROW, JR
    LAKE, CH
    CHURCHILL, MR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07): : 773 - 775
  • [5] Structural rigidity and luminescence of chiral lanthanide tetraamide complexes based on 1,4,7,10-tetraazacyclododecane
    Dickins, RS
    Howard, JAK
    Lehmann, CW
    Moloney, J
    Parker, D
    Peacock, RD
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (05): : 521 - 523
  • [6] Luminescent europium tetraazamacrocyclic complexes with wide range pH sensitivity
    Gunnlaugsson, T
    Parker, D
    [J]. CHEMICAL COMMUNICATIONS, 1998, (04) : 511 - 512
  • [7] STRUCTURE AND DYNAMICS OF LANTHANOID TETRAAZACYCLODODECANETETRAACETATE DOTA COMPLEXES IN SOLUTION
    HOEFT, S
    ROTH, K
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (04): : 869 - 873
  • [8] MACROCYCLIC POLYAMINOCARBOXYLATE COMPLEXES OF IANTHANIDES AS MAGNETIC-RESONANCE-IMAGING CONTRAST AGENTS
    KUMAR, K
    TWEEDLE, MF
    [J]. PURE AND APPLIED CHEMISTRY, 1993, 65 (03) : 515 - 520
  • [9] Taking advantage of the pH and pO2 sensitivity of a luminescent macrocyclic terbium phenanthridyl complex
    Parker, D
    Williams, JAG
    [J]. CHEMICAL COMMUNICATIONS, 1998, (02) : 245 - 246
  • [10] Luminescent chemosensors for pH, halide and hydroxide ions based on kinetically stable, macrocyclic europium-phenanthridinium conjugates
    Parker, D
    Senanayake, K
    Williams, JAG
    [J]. CHEMICAL COMMUNICATIONS, 1997, (18) : 1777 - 1778
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