Hydrothermal synthesis and crystal structure of a new 3D Co(II) supramolecule bearing 2-propylimidazole-4,5-dicarboxylate

被引：6

作者：

Liu, X. F. ^{[1
,2
]}

Ma, L. F. ^{[1
]}

Wang, L. Y. ^{[1
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[2] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 09期

基金：

中国国家自然科学基金;

关键词：

ORGANIC FRAMEWORKS; METAL-COMPLEXES; POLYMER; ARCHITECTURES; CHANNELS; BEHAVIOR; ACID;

D O I：

10.1134/S1070328410090071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new supramolecule [Co(H2PIDC)(2)(H2O)(2)] center dot 3H(2)O (I) (H2PIDC- is singly deprotonated 2-propylimidazole-4,5-dicarboxylate) has been synthesized and characterized by the X-ray diffraction method. Compound I crystallizes in the tetragonal space group I4(1)/acd with the cell parameters a = 22.1665(14), c = 18.538(2) , M (r) = 543.35, V = 9108.7(14) (3), rho (c) = 1.585 g/cm(3), Z = 16, F(000) = 4528. The Co2+ ion is coordinated by two N-O chelated H2PIDC- ligands and two water oxygen atoms to form a distorted octahedral geometry. The mononuclear complexes are linked by a hydrogen bond into 1D w-shaped double-chain fragments, which are then linked by oxygen-bifurcated acceptor hydrogen bonds into a 3D framework.

引用

页码：680 / 684

页数：5

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