Syntheses and characterization of two new mixed-ligand bismuth(III) complexes, crystal structure of [Bi(phen)2(NO3)(NCS)2(MeOH)]

被引：4

作者：

Morsali, A ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Dept Chem, Sch Sci, Tehran, Iran

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2005年 / 60卷 / 04期

关键词：

bismuth(III) complexes; crystal structure; mixed-ligand complexes; pi-pi stacking;

D O I：

10.1515/znb-2005-0405

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes [Bi(phen)(2)(NO3)(NCS)(2)(MeOH)] and [Bi(phen)(2)(NO3)(2)(NCS)] have been synthesized and characterized by their IR. spectra and elemental analyses. The structure of the [Bi(phen)(2)(NO3)(NCS)(2)(MeOH)] complex has been confirmed by X-ray crystallography. The Bi atoms are unsymmetrically eight-coordinated, N6O2. The arrangement of the ligands does not show a gap in the coordination geometry around the Bi(III) ion, indicating that its lone pair of electrons is not active. The thiocyanate ligands are coordinated to the bismuth atom via the nitrogen atom. There is pi-pi stacking interactions between the parallel aromatic rings belonging to adjacent chains.

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页码：389 / 392

页数：4

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