Chelation-controlled Bergman cyclization: Synthesis and reactivity of enediynyl ligands

被引：176
作者：
Basak, A [1 ]
Mandal, S [1 ]
Bag, SS [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
来源：
CHEMICAL REVIEWS | 2003年 / 103卷 / 10期
关键词：
D O I：
10.1021/cr020069k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chelation-controlled Bergman cyclization (BC), and synthesis and reactivity of enediynyl ligands were investigated. The manganese enediyne complexes were formed by dimerization of the corresponding alkyne complex. It was shown that the reactivity difference was independent of metal center geometry.
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页码：4077 / 4094
页数：18
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