Bis(μ-4-nitropyridine N-oxide-κ2O:O)bis[dibromocopper(II)]

被引:1
|
作者
Twamley, B [1 ]
机构
[1] Univ Idaho, Univ Res Off, Moscow, ID 83844 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词
D O I
10.1107/S1600536805005441
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu2Br4(C5H4N2O3)(2)], is a centrosymmetric dimer that contains a central planar Cu2O2 rhombus with the O atom of the N-oxide group bridging two Cu atoms [ Cu - O - Cu = 109.08 (19)degrees and O - Cu - O = 70.92 ( 19)degrees]. The two-dimensional sheet structure is built up via semi-coordinate intermolecular Cu center dot center dot center dot Br bonds [3.226 ( 1) and 3.810 (1) angstrom] and weak hydrogen bonding [ C center dot center dot center dot Br = 3.733 ( 7), 3.781 ( 7) and 3.830 ( 7) angstrom].
引用
收藏
页码:M619 / M621
页数:3
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