Synthesis, characterization, and fluorescence phenomena of 1-naphthoxy and 1-naphthylamino substituted cyclotriphosphazenes

被引：6

作者：

Aslan, Fatih ^{[1
]}

Halci, Oguzhan ^{[1
]}

Arslan, Mustafa ^{[2
]}

机构：

[1] Harran Univ, Dept Chem, TR-63100 Sanliurfa, Turkey

[2] Firat Univ, Dept Chem, TR-23169 Elazig, Turkey

来源：

HETEROATOM CHEMISTRY | 2008年 / 19卷 / 02期

关键词：

D O I：

10.1002/hc.20400

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of hexachlorocyclotriphosphazene N3P3Cl6 (1) with 1-naphthol and 1-naphthylamine have been examined. The reaction of 1 with sodium 1-naphthoxy gave the hexakis(I-naphthoxy)cyclotriphosphazene (2) in high yield. Geminal 2,2-di(1-naphthylamino)-4,4,6,6-tetrachlorocyclotriphosphazene (3) was obtained from the reaction of I with 1-naphthylamine. The structures of phosphazene derivatives were defined by elemental analysis, FTIR, UV-visible, and H-1, C-13, P-31 NMR spectroscopy. The fluorescence intensity of the compounds was measured in THF and CH2 Cl-2. (C) 2008 Wiley Periodicals, Inc.

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页码：158 / 162

页数：5

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