Ignition and combustion characteristics of compound of magnesium and boron

被引:46
作者
Liu, Lin-lin [1 ]
Liu, Pei-jin [1 ]
He, Guo-qiang [1 ]
机构
[1] Northwestern Polytech Univ, Internal Flow & Thermal Struct Lab, Sci & Technol Combust, Xian 710072, Peoples R China
关键词
Compound of magnesium and boron; Ignition and combustion performance; Amorphous boron; Combustion intensity; RICH SOLID-PROPELLANT; PARTICLES; MODEL;
D O I
10.1007/s10973-015-4653-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
Compound of magnesium and boron (MB) is promising to be the ideal substitute of amorphous boron which is usually used as the raw material of boron-based fuel-rich propellants. In this study, the physical characteristics of MB and amorphous boron were studied by the scanning electron microscope, X-ray diffraction and X-ray photoelectron spectroscopy. The thermal reaction characteristics and the ignition and combustion characteristics were investigated through TG/DSC experiments and laser ignition experiments. The experimental results show that the MB particle is much more regular than amorphous boron, which favors for the preparation of boron-based fuel-rich propellants. Magnesium exists in the form of elementary substance, and boron oxide is produced during the preparation of MB which results in the longer ignition delay time of MB. The content of magnesium and the pressure have effects on the MB combustion performance. Although the combustion of magnesium can provide much heat for the combustion of boron, MB with moderate content of magnesium shows the best combustion performance. On the contrast, the ignition delay time of MB is independent on the content of magnesium and the pressure.
引用
收藏
页码:1205 / 1212
页数:8
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