LED lighting as a simple, inexpensive, and sustainable alternative for Wolff rearrangements

被引：53

作者：

Bernardim, Barbara ^{[1
]}

Hardman-Baldwin, Andrea M. ^{[2
]}

Burtoloso, Antonio C. B. ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

[2] Ohio State Univ, Dept Chem & Biochem, Columbus, OH 43210 USA

来源：

RSC ADVANCES | 2015年 / 5卷 / 18期

基金：

巴西圣保罗研究基金会;

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; BETA-AMINO ACIDS; HETEROAROMATIC-COMPOUNDS; DIAZOKETONES; HOMOLOGATION; PHOTOLYSIS; CHEMISTRY; MECHANISM;

D O I：

10.1039/c4ra15670f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Wolff rearrangement is one of the best methods for chain homologation. However, it still suffers from many drawbacks with respect to its practical execution in the laboratory. We wish to demonstrate the use of commercial LED lamps as a sustainable alternative for the classic experimental protocols typically used for Wolff rearrangements.

引用

页码：13311 / 13314

页数：4

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