Selectivity adjustment in the cleavage of allyl phenyl and methyl phenyl ethers with boron trifluoride-methyl sulfide complex

被引：16
|
作者：
Konieczny, MT [1 ]
Maciejewski, G [1 ]
Konieczny, W [1 ]
机构：
[1] Med Acad Gdansk, Dept Organ Chem, PL-80416 Gdansk, Poland
来源：
SYNTHESIS-STUTTGART | 2005年 / 10期
关键词：
ethers; cleavage; regioselectivity; substituent effects; boron trifluoride; methyl sulfide;
D O I：
10.1055/s-2005-865304
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cleavage of model allyl phenyl and methyl phenyl ethers with boron trifluoride-methyl sulfide complex is described. The demonstrated strong dependence of the reaction rate on the substitution pattern of the phenyl ring and the reaction conditions make it potentially possible to selectively cleave a single methoxy (or allyloxy) group in polymethoxy (or allyloxy) compounds.
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页码：1575 / 1577
页数：3
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