FRAGMENTATION CHAIN-TRANSFER;
MULTIWALLED CARBON NANOTUBES;
LIVING RADICAL POLYMERIZATION;
STAR BLOCK-COPOLYMERS;
END GROUP REMOVAL;
CONTROLLED MOLECULAR-WEIGHT;
AZIDE-ALKYNE CYCLOADDITION;
LIQUID-CRYSTALLINE PHASES;
WELL-DEFINED POLYMERS;
CROSS-LINKED MICELLES;
D O I:
10.1039/c0py00179a
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
This review focuses on the approaches to the synthesis of functional polymers for optoelectronic applications that make use of radical polymerization with reversible addition-fragmentation chain transfer (RAFT) polymerization. Optoelectronic applications include hole/electron transport in photovoltaics (OPVs), light emitting diodes (OLEDs and PLEDs), thin-film transistors (TFTs), sensors, light-harvesting and related applications. In this context we consider metallopolymers (polymers that incorporate a metal or possess metal ligating functionality as a pendant group to the backbone, as an end-group or as a connecting group), organic semiconductors (polymers with an organic semiconductor moiety either as a block or as a pendant group), and various surfaces, nanoparticles and quantum dots that are formed by RAFT polymerization or where a RAFT-synthesized polymer forms an integral part of the process or structure.