Functional polymers for optoelectronic applications by RAFT polymerization

被引:143
作者
Moad, Graeme [1 ]
Chen, Ming [1 ]
Haeussler, Matthias [1 ]
Postma, Almar [1 ]
Rizzardo, Ezio [1 ]
Thang, San H. [1 ]
机构
[1] CSIRO Mat Sci & Engn, Clayton, Vic 3168, Australia
关键词
FRAGMENTATION CHAIN-TRANSFER; MULTIWALLED CARBON NANOTUBES; LIVING RADICAL POLYMERIZATION; STAR BLOCK-COPOLYMERS; END GROUP REMOVAL; CONTROLLED MOLECULAR-WEIGHT; AZIDE-ALKYNE CYCLOADDITION; LIQUID-CRYSTALLINE PHASES; WELL-DEFINED POLYMERS; CROSS-LINKED MICELLES;
D O I
10.1039/c0py00179a
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This review focuses on the approaches to the synthesis of functional polymers for optoelectronic applications that make use of radical polymerization with reversible addition-fragmentation chain transfer (RAFT) polymerization. Optoelectronic applications include hole/electron transport in photovoltaics (OPVs), light emitting diodes (OLEDs and PLEDs), thin-film transistors (TFTs), sensors, light-harvesting and related applications. In this context we consider metallopolymers (polymers that incorporate a metal or possess metal ligating functionality as a pendant group to the backbone, as an end-group or as a connecting group), organic semiconductors (polymers with an organic semiconductor moiety either as a block or as a pendant group), and various surfaces, nanoparticles and quantum dots that are formed by RAFT polymerization or where a RAFT-synthesized polymer forms an integral part of the process or structure.
引用
收藏
页码:492 / 519
页数:28
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