Polysulfone-ionic liquid based membranes for CO2/N2 separation with tunable porous surface features

被引：37

作者：

Lu, Soon-Chien ^{[1
]}

Khan, Asim Laeeq ^{[2
]}

Vankelecom, Ivo F. J. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Fac Biosci Engn, Ctr Surface Chem & Catalysis, Kasteelpk Arenberg 23,Box 2461, B-3001 Leuven, Belgium

[2] COMSATS Inst Informat Technol, Dept Chem Engn, Lahore, Pakistan

来源：

JOURNAL OF MEMBRANE SCIENCE | 2016年 / 518卷

基金：

欧盟第七框架计划;

关键词：

Polysulfone; Ionic liquid; Porous membrane; Gas separation; GAS-TRANSPORT PROPERTIES; GEL MEMBRANES; CO2; SEPARATION; CARBON-DIOXIDE; COMPOSITE MEMBRANES; FLUE-GAS; 1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE; POLY(IONIC LIQUID)S; POLYMER MEMBRANES; PERFORMANCE;

D O I：

10.1016/j.memsci.2016.06.031

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A surprisingly simple, yet effective blending method for ionic liquids (ILs) and polysulfone (PSf) is presented in this paper. Not only is the IL properly immobilised in the polymer matrix, which is crucial in high-pressure gas separation applications, but this method also produces tunable porous surfaced membranes that can be useful in several other applications. The size and distribution of the pores are dependent on the type and amount of IL incorporated into the PSf. A membrane formation mechanism is proposed to explain the presence of such a regular surface pore structure. Several commercially available ILs were tested to examine their compatibility with the polymer, and the CO2/N-2 gas separation performance of the resulting membrane was screened. ATR-FTIR spectroscopy, FTIR microscopy, and SEM imaging were also employed to shed light on the observed membrane structures. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：10 / 20

页数：11

共 41 条

[1] Polyimide mixed matrix membranes for CO2 separations using carbon-silica nanocomposite fillers [J].

Anjum, M. Waqas ;

de Clippel, F. ;

Didden, J. ;

Khan, Asim Laeeq ;

Couck, Sarah ;

Baron, Gino V. ;

Denayer, Joeri F. M. ;

Sels, B. F. ;

Vankelecom, I. F. J. .

JOURNAL OF MEMBRANE SCIENCE, 2015, 495 :121-129

[2] Improving CO2 permeability in polymerized room-temperature ionic liquid gas separation membranes through the formation of a solid composite with a room-temperature ionic liquid [J].

Bara, Jason E. ;

Hatakeyama, Evan S. ;

Gin, Douglas L. ;

Noble, Richard D. .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (10) :1415-1420

[3] Synthesis and light gas separations in cross-linked gemini room temperature ionic liquid polymer membranes [J].

Bara, Jason E. ;

Hatakeyama, Evan S. ;

Gabriel, Christopher J. ;

Zeng, Xiaohui ;

Lessmann, Sonja ;

Gin, Douglas L. ;

Noble, Richard D. .

JOURNAL OF MEMBRANE SCIENCE, 2008, 316 (1-2) :186-191

[4] Synthesis and performance of polymerizable room-temperature ionic liquids as gas separation membranes [J].

Bara, Jason E. ;

Lessmann, Sonja ;

Gabriel, Christopher J. ;

Hatakeyama, Evan S. ;

Noble, Richard D. ;

Gin, Douglas L. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (16) :5397-5404

[5] Guide to CO2 Separations in Imidazolium-Based Room-Temperature Ionic Liquids [J].

Bara, Jason E. ;

Carlisle, Trevor K. ;

Gabriel, Christopher J. ;

Camper, Dean ;

Finotello, Alexia ;

Gin, Douglas L. ;

Noble, Richard D. .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (06) :2739-2751

[6] Gas transport properties of Pebax®/room temperature ionic liquid gel membranes [J].

Bernardo, Paola ;

Jansen, Johannes Carolus ;

Bazzarelli, Fabio ;

Tasselli, Franco ;

Fuoco, Alessio ;

Friess, Karel ;

Izak, Pavel ;

Jarmarova, Veronika ;

Kacirkova, Marie ;

Clarizia, Gabriele .

SEPARATION AND PURIFICATION TECHNOLOGY, 2012, 97 :73-82

[7] Gas solubilities in room temperature ionic liquids - Correlation between RTiL-molar mass and Henry's law constant [J].

Blath, Jessica ;

Christ, Michael ;

Deubler, Natalie ;

Hirth, Thomas ;

Schiestel, Thomas .

CHEMICAL ENGINEERING JOURNAL, 2011, 172 (01) :167-176

[8] CO2/light gas separation performance of cross-linked poly(vinylimidazolium) gel membranes as a function of ionic liquid loading and cross-linker content [J].

Carlisle, Trevor K. ;

Nicodemus, Garret D. ;

Gin, Douglas L. ;

Noble, Richard D. .

JOURNAL OF MEMBRANE SCIENCE, 2012, 397 :24-37

[9] High pressure phase behavior of carbon dioxide in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and 1-butyl-3-methylimidazolium dicyanamide ionic liquids [J].

Carvalho, Pedro J. ;

Alvarez, Victor H. ;

Marrucho, Isabel M. ;

Aznar, Martin ;

Coutinho, Joao A. P. .

JOURNAL OF SUPERCRITICAL FLUIDS, 2009, 50 (02) :105-111

[10] PVDF/ionic liquid polymer blends with superior separation performance for removing CO2 from hydrogen and flue gas [J].

Chen, Hang Zheng ;

Li, Pei ;

Chung, Tai-Shung .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (16) :11796-11804

← 1 2 3 4 5 →